• 专利标题:   Concentrating stabilized solution of graphene oxide having continuous phase, comprises adding absorbent material to solution, and absorbing portion of the phase with material to form solution having higher graphene oxide concentration.
  • 专利号:   WO2016077867-A1, AU2015349597-A1, KR2017086041-A, EP3229945-A1, US2017312695-A1, JP2018502032-W, EP3229945-A4
  • 发明人:   MAJUMDER M, AKBARIVAKILABADI A
  • 专利权人:   UNIV MONASH, UNIV MONASH
  • 国际专利分类:   B01D071/02, B82Y030/00, C01B031/00, C09K019/00, B01D061/02, B01D067/00, B01D069/14, B01D071/38, B01D071/40, C01B032/182, C01B032/00, C01B032/198, C09K019/52, B01D069/10, B01D069/12, B01D071/06, C01B032/194, C01B032/192, C01B032/23
  • 专利详细信息:   WO2016077867-A1 26 May 2016 B01D-071/02 201638 Pages: 70 English
  • 申请详细信息:   WO2016077867-A1 WOAU000698 19 Nov 2015
  • 优先权号:   AU904644, WOAU000698

▎ 摘  要

NOVELTY - Concentrating (M1) a stabilized solution of graphene oxide including a continuous phase and having an initial graphene and/or graphene oxide concentration, comprises adding an absorbent material to the solution, and absorbing at least a portion of the continuous phase from the solution with the absorbent material to form a solution having a graphene oxide concentration that is greater than the initial graphene oxide concentration. USE - The method is useful for concentrating the stabilized solution of graphene oxide, which is useful for forming the film on a substrate surface, preferably a graphene oxide film or a reduced graphene oxide film. The graphene oxide film or the reduced graphene oxide film is useful as a membrane in a membrane separation process (all claimed). ADVANTAGE - The method: concentrates the solution of graphene oxide without the application of heat or vacuum; results in converting a dilute suspension of graphene oxide into a viscoelastic, liquid crystalline fluid, e.g. a concentrated solution of discotic nematic phase graphene oxide; and is applied to make a large area membrane, as the volume of fluid required is small. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) forming (M2) a film of a stabilized solution of graphene oxide on a substrate surface, comprising applying the solution of graphene oxide to the substrate surface, drawing the solution through a channel defined by two opposing surfaces having a gap between them at a shear rate, where a first opposing surface of the channel is the substrate surface, and forming a film of the solution having a thickness corresponding to a length of the gap; (2) a graphene oxide film or a reduced graphene oxide film formed by the method (M2); and (3) a graphene oxide membrane including a graphene oxide layer on a support layer, where the graphene oxide layer includes aligned discotic graphene oxide particles.