• 专利标题:   Preparing degradable polybutylene adipate terephthalate useful in preparing film products, comprises esterifying terephthalic acid, butanediol, catalyst and stabilizer with zinc oxide-graphene and esterifying adipic acid, butanediol, catalyst, and stabilizer and esterifying obtained prepolymers.
  • 专利号:   CN115449059-A, CN115449059-B
  • 发明人:   LIU W, RAO J
  • 专利权人:   ZHONGSHAN HONGYI FILM TECHNOLOGY CO LTD
  • 国际专利分类:   C08G063/183, C08G063/78, C08J005/18, C08K003/04, C08K003/22, C08L067/02
  • 专利详细信息:   CN115449059-A 09 Dec 2022 C08G-063/183 202310 Chinese
  • 申请详细信息:   CN115449059-A CN11020850 24 Aug 2022
  • 优先权号:   CN11020850

▎ 摘  要

NOVELTY - Preparing degradable polybutylene adipate terephthalate comprises (i) dispersing graphene oxide in a first solvent to prepare a dispersion liquid; (ii) adding zinc acetate to the dispersion liquid, adjusting the pH to neutral, carrying out hydrothermal treatment, adding a reducing agent to react, separating the solid phase, and calcining under an inert atmosphere to obtain zinc oxide-graphene; (iii) mixing terephthalic acid, butanediol, the first catalyst and the first stabilizer with the zinc oxide-graphene, and the first esterification reaction to obtain the first prepolymer; (iv) mixing adipic acid, butanediol, the second catalyst, and the second stabilizer to carry out the second esterification reaction to obtain the second prepolymer; and (v) mixing the first prepolymer is mixed with the second prepolymer to carry out the third esterification reaction. USE - The method is useful for preparing degradable polybutylene adipate terephthalate is useful in the preparation of film products or injection molded products (claimed). ADVANTAGE - The method prepares degradable polybutylene adipate terephthalate with high strength, high toughness, high water resistance and degradability which can absorb ultraviolet radiation and reduce the absorption of polyester matrix to ultraviolet and the transmittance of ultraviolet to improve the aging resistance.