• 专利标题:   Nanocomposite material useful in energy storage device such as electrochemical device and lithium ion battery, comprises metal oxide bonded to graphene layer.
  • 专利号:   WO2010014215-A2, US2010081057-A1, WO2010014215-A3, CA2732504-A1, KR2011039568-A, EP2318311-A2, US2011111299-A1, CN102112393-A, US8257867-B2, US2012295096-A1, US8450014-B2, US8557442-B2, US2014030181-A1, CN102112393-B, US9070942-B2, KR1617484-B1, CA2732504-C
  • 发明人:   AKSAY I A, CHOI D, LIU J, WANG D, YANG Z, AKSAY I, GRAFF G L, NIE Z, VISWANATHAN V V, ZHANG J, XU W, KIM J Y
  • 专利权人:   BATTELLE MEMORIAL INST, UNIV PRINCETON, LIU J, AKSAY I A, CHOI D, WANG D, YANG Z, BATTELLE MEMORIAL INST, WANG D, GRAFF G L, NIE Z, VISWANATHAN V V, ZHANG J, XU W, KIM J Y, BATTELLE MEMORIAL INST, UNIV PRINCETON BATTELLE MEMORIAL INST, UNIV PRINCETON, AKSAY I A
  • 国际专利分类:   C01B031/02, C01B031/04, H01M010/00, H01M010/052, H01M010/36, H01M016/00, B32B005/16, B32B009/00, C01B031/00, C08K003/04, C08K003/20, H01M004/24, H01M004/48, H01M004/62, H01M004/583, H01M004/131, B23P017/04, H01M004/02, H01M004/13, H01M004/58, H01M006/00, B05D003/10, B32B003/26, B32B009/04, B82Y030/00, B82Y040/00, H01G004/28, H01S004/00, B05D007/00, H01M004/36, H01M010/0525, H01M010/42, H01M004/485, H01M004/587
  • 专利详细信息:   WO2010014215-A2 04 Feb 2010 C01B-031/02 201012 Pages: 46 English
  • 申请详细信息:   WO2010014215-A2 WOUS004369 28 Jul 2009
  • 优先权号:   US084140P, US460993, US901526, CA2732504, KR704537, US559528, US043707

▎ 摘  要

NOVELTY - A nanocomposite material comprises a metal oxide bonded to a graphene layer. USE - In energy storage device such as electrochemical device and lithium ion battery, and for making lithium ion battery electrode (claimed). ADVANTAGE - The graphene layer of the nanocomposite material has a carbon to oxygen ratio of 15-500:1 (preferably 20-500:1); and has a surface area of 400-2630 (preferably 600-2630) m2/g. The nanocomposite material exhibits a specific capacity at least twice that of a titania material without the graphene layer at a charge/discharge rate greater than 10C; and improves high-rate performance, electrochemical impedance spectroscopy measurements on rutile titanium dioxide (TiO2)-functionalized graphene sheets (FGS) hybrid materials were performed after cycles. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a method of forming a nanocomposite material involving providing graphene in a first suspension; dispersing the graphene with a surfactant; adding a metal oxide precursor to the dispersed graphene to form a second suspension; and precipitating the metal oxide from the second suspension onto at least one surface of the dispersed graphene to form a nanocomposite material comprising at least one metal oxide bonded to at least one graphene layer; (2) an energy storage device comprising a nanocomposite material having an active metal compound and at least one graphene layer arranged in a nanoarchitecture; and (3) a lithium ion battery electrode comprising at least one graphene layer bonded to titania to form a nanocomposite material, where the graphene layer has a carbon to oxygen ratio of 15-500:1, and a surface area of 400-2630 m2/g, and the nanocomposite material has a specific capacity at least twice that of a titania material without the graphene layer at a charge/discharge rate greater than 10C.