• 专利标题:   Producing two-dimensional iron-doped graphene involves stirring sodium butyrate with hydrotalcite on water bath and then aging stirred material and separating precipitate from liquid.
  • 专利号:   CN104828813-A
  • 发明人:   HUANG W, LI H, PENG M
  • 专利权人:   UNIV CHANGZHOU
  • 国际专利分类:   B82Y040/00, C01B031/04
  • 专利详细信息:   CN104828813-A 12 Aug 2015 C01B-031/04 201579 Pages: 5 Chinese
  • 申请详细信息:   CN104828813-A CN10229280 07 May 2015
  • 优先权号:   CN10229280

▎ 摘  要

NOVELTY - Producing two-dimensional iron-doped graphene involves stirring 0.5-1 mmol sodium butyrate with hydrotalcite at 60-70 degrees C constant temperature on water bath for 5-6 hours and then aging the stirred material for 12-24 hours and separating the precipitate from liquid. The precipitate is washed with deionized water for 2-3 times and then the washed material is dried to obtain sodium butyrate-modified hydrotalcite. The 1g sodium butyrate-modified hydrotalcite is adedd with 3-5 ml 10-15 wt.% ferrocene and then the obtained material is stirred for 2-3 hours. USE - Method for producing two-dimensional iron-doped graphene (claimed). ADVANTAGE - The method enables to produce two-dimensional iron-doped graphene in simple manner, and with mild reaction conditions. DETAILED DESCRIPTION - Producing two-dimensional iron-doped graphene involves stirring 0.5-1 mmol sodium butyrate with hydrotalcite at 60-70 degrees C constant temperature on water bath for 5-6 hours and then aging the stirred material for 12-24 hours and separating the precipitate from liquid. The precipitate is washed with deionized water for 2-3 times and then the washed material is dried to obtain sodium butyrate-modified hydrotalcite. The 1g sodium butyrate-modified hydrotalcite is adedd with 3-5 ml 10-15 wt.% ferrocene and then the obtained material is stirred for 2-3 hours. The stirred material is dried at 60-80 degrees C for 15-30 hours and then the dried material is ground by 20-40 meshes sieve to obtain powder. The obtained powder is kept in a vacuum tubular furnace at 400-600 degrees C for sintering for 2-4 hours and then the suntered material is cooled to room temperature. The cooled material is added with 20-40% hydrochloric acid solution and then the obtained material is stirred and dried for 3-4 hours to separate precipitate. The dried material is heated at 2000-2500 degrees C for 3-4 hours and cooled to obtain the desired product.