• 专利标题:   Method for preparing graphene-loaded graphite carbon coated ferroferric oxide cathode material that is utilized in lithium ion battery, involves preparing suspension and microemulsion followed by microwave reacting and passing to pyrolysis.
  • 专利号:   CN106848303-A
  • 发明人:   CAO L, QI H, LI J, HUANG J, CHEN W, MA M, LI C, DU X
  • 专利权人:   UNIV SHAANXI SCI TECHNOLOGY
  • 国际专利分类:   H01M004/525, H01M004/62
  • 专利详细信息:   CN106848303-A 13 Jun 2017 H01M-004/525 201761 Pages: 10 Chinese
  • 申请详细信息:   CN106848303-A CN10038866 17 Jan 2017
  • 优先权号:   CN10038866

▎ 摘  要

NOVELTY - A graphene-loaded graphite carbon coated ferroferric oxide cathode material preparing method involves dissolving commercially available graphene oxide in ethanol, sonicating to graphene oxide dispersion a homogeneous suspension. Analytically pure soluble iron salts, urea, and surfactant are added to deionized water, stirred to fully dissolve the iron salt, and added to the suspension, oleic acid is added to obtain microemulsion, followed by performing microemulsion microwave reaction to give the product, mixing the product with urea or melamine, and subjecting to sealed pyrolysis. USE - Method for preparing graphene-loaded graphite carbon coated ferroferric oxide cathode material that is utilized in lithium ion battery. ADVANTAGE - The material exhibits stable structure to the battery, improves the cycle stability and can be prepared in simple and cost effective manner. DETAILED DESCRIPTION - A graphene-loaded graphite carbon coated ferroferric oxide cathode material preparing method involves dissolving commercially available graphene oxide in ethanol, sonicating to graphene oxide dispersion a homogeneous suspension. Analytically pure soluble iron salts, urea, and surfactant are added to deionized water, stirred to fully dissolve the iron salt, and added to the suspension, oleic acid is added to obtain microemulsion, where the volume ratio of oleic acid and water is (1-4): (1-4), the concentration of iron salt is 0.05-0.5 mol/L, concentration of urea is 0.05-0.5 mol/L, concentration of the surface active agent is 0.05-0.2 g/L, a concentration of graphene oxide is 0.5-2.5 mg/mL, followed by performing microemulsion microwave reaction to give the product, mixing the product with urea or melamine at mass ratio of 1: (1-5), grinding, subjecting to sealed pyrolysis to obtain finished product.