• 专利标题:   Composite material useful as damping engineering material, comprises styrene-ethylene-butylene-styrene and graphene, both grafted with multiple hydrogen bond molecules.
  • 专利号:   CN112300525-A, CN112300525-B
  • 发明人:   ZENG Y, ZHANG T, WANG H, ZHANG J, HAO Y, SUN X
  • 专利权人:   INST METAL RES CHINESE ACAD SCI
  • 国际专利分类:   C08K003/04, C08K009/04, C08L051/00, C08F292/00, C08F279/02
  • 专利详细信息:   CN112300525-A 02 Feb 2021 C08L-051/00 202129 Pages: 13 Chinese
  • 申请详细信息:   CN112300525-A CN11165737 27 Oct 2020
  • 优先权号:   CN11165737

▎ 摘  要

NOVELTY - A graphene/styrene-ethylene-butylene-styrene (SEBS) composite material comprises 100 pts. wt. SEBS grafted with multiple hydrogen bond molecules, and 0.1-2 pts. wt. graphene grafted with multiple hydrogen bond molecules. USE - The graphene/SEBS composite material is useful as high performance damping engineering material. ADVANTAGE - The graphene/SEBS composite material has high strength and damping characteristics, and adopts SEBS substrate, which has high mechanical property. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the graphene/SEBS composite material, which involves: (1) adding multiple hydrogen bond molecules and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide to an aqueous dispersion of graphene oxide (GO), ultrasonically dispersing for 0.5-1 hour, stirring and reacting for 4-12 hours to obtain a GO modified by multiple hydrogen bond molecules, adding vitamin C, stirring and reacting for 10-24 hours, suction filtering the product, cleaning, and drying to obtain graphene grafted with molecules; (2) taking SEBS as raw material, grafting maleic anhydride (MAH) on SEBS molecular chain by solution method or melt blending method to obtain MAH grafted SEBS (MAH-SEBS), taking MAH-SEBS as a precursor, grafting and modifying on the SEBS molecular chain segment by solution method or melt blending method to obtain the SEBS grafted with molecules; and (3) ultrasonically dispersing the graphene grafted with molecules in N,N-dimethylformamide (DMF), dissolving the SEBS grafted with molecules in xylene, mixing the two solution, ultrasonically processing for 0.5-2 hours until the graphene is uniformly dispersed in organic solvent system, stirring at 60-80 degrees C for 1-3 hours, pouring the mixture into ethanol to precipitate, separating the product by suction filtering, drying, hot pressing, and molding.