• 专利标题:   Preparation of five-membered cyclic carbonate using chemical fixing carbon dioxide by converting propargyl alcohol using carbon nanotube or graphene grafted with N-heterocyclic carbene in the presence of carbon dioxide and organic phase.
  • 专利号:   CN106928179-A, CN106928179-B
  • 发明人:   CHEN A, ZHANG Z, YU Y, CHEN J
  • 专利权人:   UNIV HEBEI SCI TECHNOLOGY, UNIV HEBEI SCI TECHNOLOGY
  • 国际专利分类:   C07D317/36
  • 专利详细信息:   CN106928179-A 07 Jul 2017 C07D-317/36 201757 Pages: 10 Chinese
  • 申请详细信息:   CN106928179-A CN10151017 14 Mar 2017
  • 优先权号:   CN10151017

▎ 摘  要

NOVELTY - A five-membered cyclic carbonate is prepared using chemical fixing carbon dioxide by converting propargyl alcohol using carbon nanotube or graphene as carrier grafted with N-heterocyclic carbene as catalyst in the presence of carbon dioxide and organic phase into sealed high pressure kettle at 20-100 degrees C for 4-28 hours at 0.1-5 MPa. The mass ratio of catalyst to propargyl alcohol is 60-100:45. The silver load quantity in catalyst is 5-12%. USE - Method for preparing five-membered cyclic carbonate using chemical fixing carbon dioxide (claimed). ADVANTAGE - The method is easy to realize, economical and environment-friendly, and has relatively mild reaction conditions, optimal conversion rate reaching 99.9%, selectivity reaching 100% and high atom using rate and catalytic efficiency.