• 专利标题:   Production of graphene involves stirring liquid polyacrylonitrile oligomer solution, grinding obtained thermally oxidized polyacrylonitrile oligomer, sieving, drying resultant material, and calcining obtained thermal oxide precursor.
  • 专利号:   CN104276566-A, US2016068396-A1, EP2995587-A1, JP2016056087-A, CN104276566-B, JP6065244-B2, US9630852-B2
  • 发明人:   HE C, HU C, LIU J, XU J, ZHANG Q
  • 专利权人:   LIU J, LIU J H, SHENZHEN EIGEN EQUATION GRAPHENE TECHNOL, SHENZHEN EIGEN EQUATION GRAPHENE TECHNOL, SHENZHEN EIGENEQUATION GRAPHENE TECHNOL
  • 国际专利分类:   C01B031/04, C01B031/02, C01B032/15, C01B032/18, C01B032/182
  • 专利详细信息:   CN104276566-A 14 Jan 2015 C01B-031/04 201528 Pages: 13 Chinese
  • 申请详细信息:   CN104276566-A CN10454395 09 Sep 2014
  • 优先权号:   CN10454395

▎ 摘  要

NOVELTY - Production of graphene involves stirring liquid polyacrylonitrile oligomer (LPAN) solution at 80-300 degrees C for 8-72 hours, stirring obtained micro-cyclized LPAN solution at 200-300 degrees C for 1-10 hours, grinding obtained thermally oxidized polyacrylonitrile oligomer, sieving, drying resultant material at room temperature, calcining obtained thermal oxide precursor at 400-1000 degrees C for 1-24 hours, and calcining obtained low-temperature carbonization precursor at 1000-3000 degrees C for 1-10 hours. USE - Production of graphene (claimed). ADVANTAGE - The method enables production of graphene with high electroconductivity, by simple process. DETAILED DESCRIPTION - Production of graphene involves stirring liquid polyacrylonitrile oligomer (LPAN) solution at 80-300 degrees C for 8-72 hours, stirring obtained micro-cyclized LPAN solution at 200-300 degrees C for 1-10 hours, obtaining thermally oxidized polyacrylonitrile oligomer having trapezoidal structure, grinding thermally oxidized polyacrylonitrile oligomer, sieving, drying resultant material at room temperature, calcining obtained thermal oxide precursor at 400-1000 degrees C and gas flow rate of 10-500 ml/minute for 1-24 hours under inert gas protection atmosphere, and calcining obtained low-temperature carbonization precursor at 1000-3000 degrees C and gas flow rate of 10-500 ml/minute for 1-10 hours under inert gas protection atmosphere.