• 专利标题:   Rubber composition used for tire innerliners, comprises graphene as plate, butyl rubber, carbon black, naphthenic oil, hydrocarbon resins, phenolic tackifier, accelerator, stearic acid, zinc oxide and sulfur, where graphene of specific thickness and particle size comprises preset amount of carbon.
  • 专利号:   US2022363874-A1, WO2022241426-A1, US11655355-B2
  • 发明人:   HALASA A F, PASCHALL D
  • 专利权人:   AKRON POLYMER SOLUTIONS INC, AKRON POLYMER SOLUTIONS INC
  • 国际专利分类:   C08L009/00, C08K003/04, C08K003/06, C08K003/22, C08K005/09, C08K005/13, C08L101/02, C08L023/22, C08L091/00
  • 专利详细信息:   US2022363874-A1 17 Nov 2022 C08L-009/00 202200 English
  • 申请详细信息:   US2022363874-A1 US662865 11 May 2022
  • 优先权号:   US187073P, US662865

▎ 摘  要

NOVELTY - A graphene -containing rubber composition comprises butyl rubber and graphene as plate. The rubber composition further comprises butyl rubber, carbon black, naphthenic oil, aromatic hydrocarbon resin, aliphatic hydrocarbon resin, phenolic tackifier, accelerator, stearic acid, zinc oxide and sulfur. The graphene of the composition, has thickness less than 3.2 nm, particle size 50-nm - 10 μm, and comprises more than 95 wt.% carbon. USE - Rubber composition is used in tire innerliners of new generation vehicles such as electric powered automobiles. ADVANTAGE - The presence of graphene as an additive in rubber composition, enables the composition to provide increased barrier protection for tire innerliners, with no tradeoffs in other characteristics. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the method used for compounding rubber, which involves: 1) blending butyl rubber with graphene; 2) exfoliating graphene into plates, by adding carboxylic acid, ketone, aldehyde, or hydroxyl groups on the graphene plate surface or graphene plate edges; and 3) aligning the graphene plates into perpendicular alignment, such that the graphene plates provide a barrier to migration of oxygen, nitrogen, moisture or water vapor molecules.