• 专利标题:   Graphene-modified rubber material for three dimensional printing involves washing waste rubber, drying, crushing, sieving to obtain rubber powder, adding surfactant to obtain activated rubber powder and crushing graphene to obtain powder.
  • 专利号:   CN107057146-A
  • 发明人:   ZHONG Z
  • 专利权人:   GUANGXI FENGDA 3D TECHNOLOGY CO LTD
  • 国际专利分类:   B29B007/28, B29B009/06, B33Y070/00, B33Y080/00, C08K013/06, C08K003/04, C08K003/34, C08K007/06, C08K009/00, C08L019/00, C08L067/02, C08L067/04, C08L079/08
  • 专利详细信息:   CN107057146-A 18 Aug 2017 C08L-019/00 201769 Pages: 12 Chinese
  • 申请详细信息:   CN107057146-A CN10340582 15 May 2017
  • 优先权号:   CN10340582

▎ 摘  要

NOVELTY - Graphene-modified rubber material involves washing 72-135 pts. wt. waste rubber. The washed waste rubber is dried until its water content becomes 0.8%. The dried waste rubber is crushed and sieved through 200-300 mesh to obtain rubber powder. The obtained rubber powder is added with 1-1.6 pts. wt. surfactant at 72-78 degrees C at a rotational speed of 140-200 revolutions/minutes to obtain activated rubber powder. The 1.6-3.8 pts. wt. graphene is crushed over 200-300 mesh to obtain powder. USE - Graphene-modified rubber material for three dimensional printing (claimed). DETAILED DESCRIPTION - Graphene-modified rubber material involves washing 72-135 pts. wt. waste rubber. The washed waste rubber is dried until its water content becomes 0.8%. The dried waste rubber is crushed and sieved through 200-300 mesh to obtain rubber powder. The obtained rubber powder is added with 1-1.6 pts. wt. surfactant at 72-78 degrees C at a rotational speed of 140-200 revolutions/minutes to obtain activated rubber powder. The 1.6-3.8 pts. wt. graphene is crushed over 200-300 mesh to obtain powder. The obtained powder is treated ultrasonically under a power of 520-650 watt at 52-56 degrees C under a rotation speed of 200-300 revolutions/ minutes with stirring for 42-55 minutes to obtain graphene energy powder. The 32-50 pts. wt. polylactic acid, 30-42 pts. wt. dimeric sodium phosphate, 15-22 pts. wt. 2-hydroxy-4-octyloxybenzobutanone, 18-30 pts. wt. butenyl bis-stearamide, 6-12 pts. wt. of polybutylene terephthalate resin, 12-18 pts. wt. acrylic acid stearate, 9-15 pts. wt. tris (2,4-di-tert-butylphenyl) phosphite, 7-12 pts. wt. polyimide fiber, 6-9 pts. wt. carbon fiber, 0.5-0.9 pts. wt. regulator, 0.4-0.6 pts. wt. generating agent, 0.4-.7 pts. wt. crosslinking agent, 0.5-1 pts. wt. compatibilizer, 0.6-1.2 pts. wt. bridging agent, 0.2-0.4 pts. wt. catalyst, 0.4-0.8 pts. wt. of dispersant, 0.3-0.6 pts. wt. plasticizer and 0.4-0.6 pts. wt. tackifier are mixed in microwave at 142-146 degrees C under a power of 320-380 watt at a rotating speed of 200-400 revolutions/minutes for 2.5-3.6 hours to obtain first mixture. The obtained first mixture is mixed with 1-2.2 pts. wt. curing agent, 0.2-0.4 pts. wt. antioxidant, 0.3-0.5 pts. wt. stabilizer, 0.8-1.2 pts. wt. anti-aging agent, 1.4-1.8 pts. wt. flame retardant and 1.7-3.5 pts. wt. smoke suppressing agent at 73-82 degrees 9C with stirring at a rotational speed of 160-240 revolutions/minutes for 1.8-2.2 hours to obtain second mixture. The obtained second mixture is placed in screw extruder and subjected to extrusion molding at 190-200 degrees C at a rotational speed of 130-140 revolutions/ minutes to obtain graphene modified rubber material.