• 专利标题:   Preparing catalyst useful for diisopropylbenzene oxidation to prepare 2,2'-(phenylene)dipropan-2-ol, comprises reacting 1-isocyanato-5-aminonaphthalene with graphene oxide, and reacting with metal ions including copper(II) ion, manganese(II) ion, cobalt(II) ion and/or iron(III) ion.
  • 专利号:   CN114073983-A, CN114073983-B
  • 发明人:   LI Y, FENG M, LI J, FU S, CAO H
  • 专利权人:   WANHUA CHEM GROUP CO LTD
  • 国际专利分类:   B01J031/02, B01J035/10, C07C029/50, C07C033/26
  • 专利详细信息:   CN114073983-A 22 Feb 2022 B01J-031/02 202266 Chinese
  • 申请详细信息:   CN114073983-A CN10824810 17 Aug 2020
  • 优先权号:   CN10824810

▎ 摘  要

NOVELTY - Preparing catalyst comprises (1) reacting 1-isocyanato-5-aminonaphthalene with graphene oxide to obtain modified graphene oxide (GO-NDI), and (2) reacting the modified graphene oxide obtained in step (1) with metal ions to obtain graphene-supported metal catalyst. USE - The catalyst is useful for diisopropylbenzene oxidation to prepare 2,2'-(phenylene)dipropan-2-ol (claimed). ADVANTAGE - The catalyst: significantly improves the selectivity of 2,2'-(phenylene)dipropan-2-ol and reduces the accumulation of peroxides; and mainly solves the problems of complex production process of diisopropylbenzene oxidation reaction and mismatch of redox speed. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) catalyst prepared by above method. The1-isocyanato-5-aminonaphthalene and metal based catalyst is of formula (I); and (2) preparing 2,2'-(phenylene)dipropan-2-ol by oxidation of diisopropylbenzene, comprising adding diisopropylbenzene, sodium hydroxide solution and the catalyst to a reactor, introducing oxygen to carry out the oxidation reaction. A = graphene oxide; and M = Mn, Fe, Cu or Co metal ions.