• 专利标题:   Preparation of tin oxide/graphene/tin oxide negative electrode material for lithium ion battery, involves dissolving tin chloride pentahydrate to obtain mixed solution and subjecting mixed solution to centrifugal reaction.
  • 专利号:   CN105810916-A, CN105810916-B
  • 发明人:   ZHANG J, LIU X
  • 专利权人:   UNIV QINGDAO, UNIV QINGDAO
  • 国际专利分类:   B82Y030/00, H01M010/0525, H01M004/36, H01M004/48, H01M004/62
  • 专利详细信息:   CN105810916-A 27 Jul 2016 H01M-004/36 201661 Pages: 8 Chinese
  • 申请详细信息:   CN105810916-A CN10334964 19 May 2016
  • 优先权号:   CN10334964

▎ 摘  要

NOVELTY - Preparation of tin oxide/graphene/tin oxide negative electrode material for lithium ion battery, involves transferring graphene oxide solution to reaction bottle, adding tin chloride pentahydrate in the reaction bottle and dissolving completely to obtain a mixed solution, heating the mixed solution and subjecting to centrifugal reaction, washing the centrifuged solution with deionized water and ethanol at a temperature of 40-60 degrees C to obtain black powder sample, introducing argon gas and calcining at 400 degrees C for 1 hour to obtain tin oxide/graphene/tin oxide negative electrode material. USE - Preparation of tin oxide/graphene/tin oxide negative electrode material for lithium ion battery (claimed). ADVANTAGE - The preparation process is featured with simple process, short time-consuming, low production cost and easy batch production. The agglomeration of graphene, and graphene enhanced electric conductivity of electrode material can be prevented effectively, so as to improve the charge-discharge performance of materials. DETAILED DESCRIPTION - Preparation of tin oxide/graphene/tin oxide negative electrode material for lithium ion battery, involves preparing 0.5-1.5 mg/mL graphene oxide solution using Hummers method, transferring graphene oxide solution to a 20 ml reaction bottle, adding 0.1-0.6 g tin chloride pentahydrate in the reaction bottle and dissolving completely to obtain a mixed solution, placing the mixed solution into a microwave synthesis apparatus, heating the mixed solution to a temperature of 160-185 degrees C for 10-20 minutes, subjecting the mixed solution to centrifugal reaction at 8000 rpm after the reaction, washing the centrifuged solution with deionized water and ethanol for 2 times at a temperature of 40-60 degrees C for 12 hours to obtain black powder sample, placing the sample into a tube furnace, introducing argon gas and calcining at 400 degrees C for 1 hour to obtain tin oxide/graphene/tin oxide negative electrode material.