• 专利标题:   Preparing nano-silver modified graphene fiber comprises e.g. dispersing graphene oxide in deionized water to prepare graphene oxide spinning liquid, extruding the spinning liquid of graphene oxide prepared through spinning pipe.
  • 专利号:   CN107059160-A, CN107059160-B
  • 发明人:   BU Q
  • 专利权人:   BU Q, BU Q
  • 国际专利分类:   D01D001/02, D01D010/06, D01D005/06, D01F001/10, D01F011/12, D01F011/16, D01F009/12
  • 专利详细信息:   CN107059160-A 18 Aug 2017 D01F-009/12 201760 Pages: 7 Chinese
  • 申请详细信息:   CN107059160-A CN10213075 01 Apr 2017
  • 优先权号:   CN10213075

▎ 摘  要

NOVELTY - Preparing nano-silver modified graphene fiber comprises e.g. (i) dispersing graphene oxide in deionized water to prepare graphene oxide spinning liquid; (ii) extruding the spinning liquid of graphene oxide prepared in the step (i) through spinning pipe having diameter of 5-5000 mu , length of 0.5-100 cm into coagulation bath for 5-3600 seconds to obtain oxidized graphene colloid fiber; (iii) adding oxidized graphene colloid fiber obtained in step (ii) into silver ammonia solution, reducing agent, reducing silver ion to nano silver particles at 10-90 degrees C for 5-180 minutes and cleaning. USE - The method is useful for preparing nano-silver modified graphene fiber (claimed). ADVANTAGE - The nano-silver modified graphene fiber is firm, has good mechanical performance and good electrical performance. DETAILED DESCRIPTION - Preparing nano-silver modified graphene fiber comprises (i) dispersing graphene oxide in deionized water to prepare graphene oxide spinning liquid; (ii) extruding the spinning liquid of graphene oxide prepared in the step (i) through spinning pipe having diameter of 5-5000 mu , length of 0.5-100 cm into coagulation bath for 5-3600 seconds to obtain oxidized graphene colloid fiber; (iii) adding oxidized graphene colloid fiber obtained in step (ii) into silver ammonia solution, reducing agent, reducing silver ion to nano silver particles at 10-90 degrees C for 5-180 minutes, cleaning to obtain fiber surface with nano silver-modified graphene colloid fiber; (iv) drying nano silver-modified graphene colloid fiber prepared in the step (iii) at 40-100 degrees C to obtain solid graphite fiber and reducing nano silver-modified graphene colloid fiber in mixed atmosphere of inert gas or inert gas and hydrogen at a temperature of 500-900 degrees C, where graphene oxide is oxidized at the outlet of the spinning tube, the velocity of liquid along the axial direction of spinning tube is 0.1-100 ml/minute, and speed along spinning tube is 0.01-200 ml/minute.