• 专利标题:   Silicon-graphene composite cathode material used for lithium ion battery, comprises specified amount of silicon powder, graphene and amorphous carbon.
  • 专利号:   CN102306757-A, CN102306757-B
  • 发明人:   GAO P, HE Y, MA Z, YANG J
  • 专利权人:   UNIV SHANGHAI JIAOTONG
  • 国际专利分类:   H01M004/38
  • 专利详细信息:   CN102306757-A 04 Jan 2012 H01M-004/38 201210 Pages: 13 Chinese
  • 申请详细信息:   CN102306757-A CN10247595 26 Aug 2011
  • 优先权号:   CN10247595

▎ 摘  要

NOVELTY - A silicon-graphene composite cathode material comprises (in weight%) silicon powder (10-99), graphene (1-90) and amorphous carbon (0-40). The silicon powder has grain size of 20 nm to 5 mu m. The graphene forms three-dimensional solid conductive network with an internal cavity. The silicon powder is coated on the cavity to form spherical or sphere-like composite granules. The grain size of composite granules is 500 nm to 15 mu m. USE - Silicon-graphene composite cathode material is used for lithium ion battery. ADVANTAGE - The lithium ion battery using the composite cathode material has high capacity, excellent cyclic performance under the current density of 200 mA/g, and capacity-retaining rate of 98%, and is prepared at high yield by simple process. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of silicon-graphene composite cathode material, which involves dispersing silicon powder, graphene oxide, amorphous carbon in solvent, uniformly stirring, spray drying at 120-220 degrees C (inlet temperature) and 80-140 degrees C (outlet temperature) to remove solvent, heating at 500-1100 degrees C, introducing protective gas, cracking gaseous, liquid or solid carbon source into amorphous carbon, performing high-temperature annealing for 1-24 hours, reducing graphene oxide, naturally cooling to room temperature to obtain silicon-graphene composite cathode material. The content of silicon powder and graphene is 1 part weight and 0.017-15 parts weight, respectively, when the content of amorphous carbon is 0. The content of silicon powder and graphene is 1 part weight and 0.01-9 parts weight, when the content of amorphous carbon is 0-40 weight%.