• 专利标题:   Preparing in-situ loaded nitrogen-doped graphene polymer conversion ceramic-based wave-absorbing material comprises e.g. generating single-source precursor using organic nitrogen source and silicon-based polymer, cracking and heating at high temperature.
  • 专利号:   CN113735597-A, CN113735597-B
  • 发明人:   HAN X, YAN N, SUN J, ZHANG Y, FU Q
  • 专利权人:   UNIV NORTHWESTERN POLYTECHNICAL
  • 国际专利分类:   C04B035/563, C04B035/571, C04B035/577, C04B035/589, C04B035/596, C04B035/622
  • 专利详细信息:   CN113735597-A 03 Dec 2021 C04B-035/589 202234 Chinese
  • 申请详细信息:   CN113735597-A CN10966123 23 Aug 2021
  • 优先权号:   CN10966123

▎ 摘  要

NOVELTY - Preparing in-situ loaded nitrogen-doped graphene polymer conversion ceramic-based wave-absorbing material comprises (i) dispersing the nitrogen source organic matter into the organic solvent, transferring into Schlenk device, adding silicon-based polymer, stirring and reacting for 2-4 hours at 60-120degrees Celsius and removing the organic solvent under the vacuum to obtain the single-source precursor; (ii) adding the single source precursor into a tubular furnace, using nitrogen as protective gas, heating to 100-400degrees Celsius at a heating speed of 3-10degrees Celsius/min, crosslinking and curing the precursor fully at the temperature for 1-5 hours, closing the heating power supply and cooling the furnace naturally to obtain the nitrogen-doped graphene by the single-source precursor PDCs is a folding structure formed by staggering and stacking a large amount of graphene sheets, grinding and sieving fully the solidified powder to obtain 200-500 meshes precursor powder. USE - The method is useful for preparing in-situ loaded nitrogen-doped graphene polymer conversion ceramic-based wave-absorbing material. ADVANTAGE - The method: can introduce nitrogen-graphene with better absorbing properties to overcome the disadvantages; and produces in-situ loaded nitrogen-doped graphene polymer conversion ceramic-based wave-absorbing material with structure which is easy to agglomerate with improved absorbing properties.