• 专利标题:   Preparing graphene flame retardant plastic master batch comprises ultrasonically treating graphene oxide and ethanol solution, adding e.g. tetraethyl orthosilicate, stirring, drying, adding methyl methacrylate and initiator and spray drying.
  • 专利号:   CN108727526-A
  • 发明人:   CHEN Q
  • 专利权人:   CHENGDU NEW KELI CHEM SCI CO LTD
  • 国际专利分类:   C08F120/14, C08F002/44, C08K003/36, C08K003/04, C08K003/26, C08J003/22
  • 专利详细信息:   CN108727526-A 02 Nov 2018 C08F-120/14 201881 Pages: 7 Chinese
  • 申请详细信息:   CN108727526-A CN10595775 11 Jun 2018
  • 优先权号:   CN10595775

▎ 摘  要

NOVELTY - Preparing graphene flame retardant plastic master batch comprises (a) adding graphene oxide to aqueous ethanol solution, ultrasonically treating, adding tetraethyl orthosilicate, aqueous ammonia and magnesium aluminum carbonate type hydrotalcite, mechanically stirring and drying at room temperature to obtain nano silicon dioxide, graphene oxide nanosheet and hydrotalcite composite and (b) adding methyl methacrylate and initiator to the composite, mixing uniformly, coating polymethyl methacrylate on the surface of the composite by in-situ polymerization, cleaning, and spray drying. USE - The method is useful for preparing graphene flame retardant plastic master batch. ADVANTAGE - The method: generates nano silicon dioxide by in-situ hydrolysis on graphene oxide nanosheets, which ensures that the nano silicon dioxide can increase the dispersibility of the graphene oxide; and uses auxiliary hydrotalcite and polymethylmethacrylate inclusions on grapheme, which is beneficial to improve dispersibility and flame retardancy of the material.