• 专利标题:   Carbon composite comprises composite preform including carbon fiber preform, and coating layer comprising secondary nanomaterial formed on surface, inside or both of carbon fiber preform.
  • 专利号:   KR2203084-B1
  • 发明人:   LEE H, KIM Y, PARK J G, BAE S
  • 专利权人:   AGENCY DEFENSE DEV
  • 国际专利分类:   D06M101/40, D06M011/74, D06M013/50
  • 专利详细信息:   KR2203084-B1 14 Jan 2021 D06M-011/74 202110 Pages: 11
  • 申请详细信息:   KR2203084-B1 KR108767 03 Sep 2019
  • 优先权号:   KR108767

▎ 摘  要

NOVELTY - Carbon composite comprises a composite preform including carbon fiber preform, and a coating layer comprising a secondary nanomaterial formed on the surface, inside or both of the carbon fiber preform, where the pores of the composite preform are filled with matrix containing carbon and/or ceramic. The two-dimensional nanomaterials include graphene, transition metal carbide, transition metal nitride, and/or transition metal carbonitride. The carbon fiber preform comprises 0.01-10 pts. wt. 2D nanomaterial. The ceramic includes silicon, zirconium, tantalum, and/or hafnium. USE - Used as carbon composite. ADVANTAGE - The carbon composite has improved oxidation resistance, heat resistance, excellent heat conduction rate, fracture toughness and excellent binding force between the composite preform and the matrix filled in the pores of the composite preform, improves mechanical properties, and can be manufactured by a simple process. DETAILED DESCRIPTION - Carbon composite comprises a composite preform including carbon fiber preform, and a coating layer comprising a secondary nanomaterial formed on the surface, inside or both of the carbon fiber preform, where the pores of the composite preform are filled with matrix containing carbon and/or ceramic. The two-dimensional nanomaterials include graphene, transition metal carbide, transition metal nitride, and/or transition metal carbonitride. The carbon fiber preform comprises 0.01-10 pts. wt. two dimensional (2D) nanomaterial. The ceramic includes silicon, zirconium, tantalum, and/or hafnium. The 2D nanomaterial is metal based compound of formula (Mn+1Xn) (I), preferably e.g. titanium carbide and vanadium carbide. M = early transition metal, preferably Sc, Ti, V, Cr, Zr, Nb, Mo, Hf, or Ta; X = C, N or CN; and n = 1-3. An INDEPENDENT CLAIM is also included for producing carbon composite, comprising (a) preparing a composite preform by coating the carbon fiber preform with a solution in which the 2D nanomaterial is dispersed, and (b) densifying the composite preform using a chemical vapor deposition method or a polymer supported pyrolysis method which is performed using pitch, polycarbosilane, polysiloxane, silazane, borosilane, and/or silica sol.