▎ 摘　　要

NOVELTY - Preparation of conductive-like shell layered graphene composite material comprises using ultrasonic method or centrifuging graphene oxide to prepare uniform aqueous solution, adopting vacuum filtration, and adding 10,12-pentacosadiyn-1-ol (PCDO); and under darkness, esterifying graphite oxide film, adjusting PCDO concentration of the solution, controlling to 5-10% in the layered composite material, under protection of inert gas, by ultraviolet light, crosslinking, and reducing hydroiodic acid to obtain high conductivity of shell layered graphene oxide composite material. USE - Method of preparation of conductive-like shell layered graphene composite material (claimed). DETAILED DESCRIPTION - Preparation of conductive-like shell layered graphene composite material comprises using ultrasonic method or centrifuging graphene oxide to prepare uniform aqueous solution, at ratio of graphene oxide and deionized water at 0.1-0.5:1000, and adopting vacuum filtration or spin coating oxidized graphite alkene aqueous solution assembled into thin film structure, with thickness of 0.5-50 mu m, and adding 10,12-pentacosadiyn-1-ol (PCDO); and under darkness, esterifying graphite oxide film, adjusting PCDO concentration of the solution, controlling to 5-10% in the layered composite material, under protection of inert gas, by ultraviolet light, crosslinking, and reducing hydroiodic acid to obtain high conductivity of shell layered graphene oxide composite material.