• 专利标题:   High-concentrated graphene/epoxy resin composite material comprises bisphenol A type liquid epoxy resin, graphene micro sheet, bisphenol A and catalyst.
  • 专利号:   CN107353587-A
  • 发明人:   KONG L
  • 专利权人:   JIANGSU XINGSHENG CHEM CO LTD
  • 国际专利分类:   C08G059/62, C08G059/68, C08K007/00, C08L063/00, C09D163/00, C09D005/10, C09D007/12
  • 专利详细信息:   CN107353587-A 17 Nov 2017 C08L-063/00 201804 Pages: 7 Chinese
  • 申请详细信息:   CN107353587-A CN10472529 21 Jun 2017
  • 优先权号:   CN10472529

▎ 摘  要

NOVELTY - High-concentrated graphene/epoxy resin composite material comprises 300 pts. wt. bisphenol A type liquid epoxy resin, 35-60 pts. wt. graphene micro sheet, 98 pts. wt. bisphenol A and 0.2 pts. wt. catalyst, where the equivalent weight of epoxy in the bisphenol A type liquid epoxy resin is 184-244, the catalyst is benzyltriphenylphosphonium bromide, benzyltriethylammonium chloride or triphenylphosphine. USE - Used as high-concentrated graphene/epoxy resin composite material. ADVANTAGE - The composite material has simple preparation method, avoids using organic solvent, and is environmentally friendly. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing high-concentrated graphene/epoxy resin composite material comprising (i) adding low molecular quantity of bisphenol A type liquid epoxy resin into a reaction kettle, opening the stirrer and stirring, opening steam and heating to 40 degrees C, (ii) adding graphene micro sheet and stirring at a speed of 20-30 revolution/minute, and heating to 80 degrees C by stirring at a rotational speed of 150 revolution/minute for 40 minutes, (iii) adding bisphenol A, stirring at a speed of 20-30 revolution/minute and melting at 80 degrees C for 30 minutes, then adding catalyst, slowly adjusting high rotating speed to 150 revolution/minute, heating to 120 degrees C, closing steam, and then reacting, and (iv) opening vacuum pump and heating at 160 degrees C under vacuum of more than 0-0.095 MP, reacting at 160-170 degrees C for 60 minutes, closing vacuum pump, filling high purity nitrogen, discharging plate, and cooling to room temperature to obtain final product.