• 专利标题:   Antistatic coating liquid useful in antistatic industry, comprises e.g. pH value regulator, conductive auxiliary agent, coupling agent, deionized water, wetting and leveling agent, antifoaming agent and matrix resin which is prepared by e.g. mixing polytetrahydrofuran and aromatic diisocyanate.
  • 专利号:   CN114213959-A
  • 发明人:   WANG P, RAO S, SUN B, YI Q
  • 专利权人:   WUHAN SINUOFUHONG SCI TECHNOLOGY CO
  • 国际专利分类:   C09D125/18, C09D165/00, C09D175/08, C09D005/24
  • 专利详细信息:   CN114213959-A 22 Mar 2022 C09D-175/08 202258 Chinese
  • 申请详细信息:   CN114213959-A CN11607580 27 Dec 2021
  • 优先权号:   CN10895774

▎ 摘  要

NOVELTY - Antistatic coating liquid comprises 5-75 pts. wt. poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT/PSS) aqueous dispersion stock solution, 0.05-0.75 pts. wt. pH value regulator, 1-8 pts. wt. conductive auxiliary agent, 5-15 pts. wt. matrix resin, 0.05-0.5 pts. wt. coupling agent, 1-20 pts. wt. deionized water, 0.05-0.5 pts. wt. wetting and leveling agent and 0.05-0.5 pts. wt. antifoaming agent. The matrix resin is prepared by: mixing dehydrated polycarbonate diol, 0.1-5 pts. wt. polytetrahydrofuran and 2-25 pts. wt. aromatic diisocyanate and heating, adding 1-10 pts. wt. dimethylol propionic acid and 0.1-5 pts. wt. epoxy resin, reacting, adding 0.1-2 pts. wt. propylene glycol, 0.1-3 pts. wt. trimethylolpropane and 0.5-5 pts. wt. acetone, reacting, cooling to obtain prepolymer, adding 0.1-2 pts. wt. triethylamine and 5-50 pts. wt. water to prepolymer and stirring to obtain white emulsion, adding 0.1-1 pt. wt. nanoparticles and stirring, and removing solvent. USE - The antistatic coating liquid is useful in antistatic industry (claimed). ADVANTAGE - The coating liquid: has stable performance, high conductivity, solvent resistance, and safety; is environmentally friendly; and has surface resistance reaching 105-106 omega, surface resistance remaining at 106-107 omega after repeated alcohol washing and no obvious atomizing phenomenon. DETAILED DESCRIPTION - Antistatic coating liquid comprises 5-75 pts. wt. poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT/PSS) aqueous dispersion stock solution, 0.05-0.75 pts. wt. pH value regulator, 1-8 pts. wt. conductive auxiliary agent, 5-15 pts. wt. matrix resin, 0.05-0.5 pts. wt. coupling agent, 1-20 pts. wt. deionized water, 0.05-0.5 pts. wt. wetting and leveling agent and 0.05-0.5 pts. wt. antifoaming agent. The matrix resin is prepared by: mixing 1-10 pts. wt. dehydrated polycarbonate diol, 0.1-5 pts. wt. polytetrahydrofuran and 2-25 pts. wt. aromatic diisocyanate and heating to 65-85degreesC, then adding 1-10 pts. wt. dimethylol propionic acid and 0.1-5 pts. wt. epoxy resin, reacting for 1-3 hours, adding 0.1-2 pts. wt. propylene glycol, 0.1-3 pts. wt. trimethylolpropane and 0.5-5 pts. wt. acetone, reacting at 60-80degrees Celsius to finish, then cooling to 50-70degrees Celsius to obtain a prepolymer, adding 0.1-2 pts. wt. triethylamine and 5-50 pts. wt. water to the prepolymer and stirring for 30-50 minutes to obtain a white emulsion, then adding 0.1-1 pt. wt. nanoparticles and stirring for 1-3 hours, and removing the solvent to obtain the finished product. INDEPENDENT CLAIMS are also included for: (1) preparing the antistatic coating liquid, comprising mixing and stirring PEDOT/PSS aqueous dispersion stock solution, pH value regulator, conductive auxiliary agent, matrix resin, coupling agent, deionized water, wetting and leveling agent and antifoaming agent to obtain the finished product; and (2) use method of the antistatic coating liquid in antistatic industry, comprising coating antistatic coating liquid on the base material with a wire rod, and drying at 100-140degrees Celsius for 0.5-1 minute to obtain an antistatic PEDOT/PSS antistatic coating, where the base material is polyethylene terephthalate, polyethylene and/or glass.