• 专利标题:   Heat-conducting and flame-retardant polyolefin-based composite material useful for cable material in vehicle, comprises e.g. polypropylene, styrene-ethylene-butadiene-styrene block copolymer, maleic anhydride grafted polypropylene, and antioxidant, ammonium polyphosphate.
  • 专利号:   CN114854125-A, CN114854125-B
  • 发明人:   LI T, ZHONG R, LIU Y
  • 专利权人:   GUANGDONG ATP POLYMER TECHNOLOGY CO LTD
  • 国际专利分类:   C08K003/04, C08K003/08, C08K007/04, C08K009/02, C08K009/04, C08K009/06, C08K009/12, C08L023/12, C08L051/06, C08L053/02, C08L087/00, H01B003/44
  • 专利详细信息:   CN114854125-A 05 Aug 2022 C08L-023/12 202287 Chinese
  • 申请详细信息:   CN114854125-A CN10539047 18 May 2022
  • 优先权号:   CN10539047

▎ 摘  要

NOVELTY - Heat-conducting and flame-retardant polyolefin-based composite material comprises 75-80 pt. wt. polypropylene, 12-18 pt. wt. styrene-ethylene-butadiene-styrene block copolymer, 7-9 pt. wt. maleic anhydride grafted polypropylene, 5 pt. wt. modified graphene, 12-15 pt. wt. modified boron nitride fiber, 2-4 pt. wt. epoxy-terminated hyperbranched auxiliary agent, 1-2 pt. wt. antioxidant, 10-13 pt. wt. ammonium polyphosphate. The epoxy-terminated hyperbranched auxiliary agent is prepared by adding hyperbranched polymer into dimethylformamide, adding boron trifluoride ethyl ether, adding epichlorohydrin under stirring, heating to 65℃ for 2 hours, removing unreacted epichlorohydrin and dimethylformamide by rotary evaporation, transferring mixture to reactor, adjusting pH to 8-9 by dropwise addition of sodium hydroxide solution, heating temperature to 80℃, maintaining reaction for 3 hours, extracting liquid, separating and distilling organic phase under reduced pressure. USE - The composite material is useful for cable material used in vehicle. ADVANTAGE - The composite material has limiting oxygen index of more than 37% and thermal conductivity of more than 2 W/m.K; improves the service life of the cable when used in cable material, and reduces the safety hazard. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a method for preparing heat-conducting and flame-retardant polyolefin-based composite material comprising (1) mixing polypropylene, styrene-ethylene-butadiene-styrene block copolymer, maleic anhydride grafted polypropylene, modified graphene, and modified boron nitride fibers, adding epoxy-terminated hyperbranched auxiliary agent, antioxidant, ammonium polyphosphate, and continue stirring to obtain a mixture, and (2) extruding and granulating the mixture with a twin-screw extruder to obtain a heat-conducting and flame-retardant polyolefin-based composite material.