• 专利标题:   Preparing porous tubular carbon nitride catalyst useful in visible light catalytic degradation of antibiotic pollutants, comprises e.g. adding melamine and cyanuric acid into deionized water, placing in oil bath, placing precursor in ceramic crucible, introducing nitrogen, and natural cooling.
  • 专利号:   CN115301267-A
  • 发明人:   XU Y, WANG C, WANG S, LI X, HAN F, XU B, ZHANG X, YU P
  • 专利权人:   UNIV NANJING TECHNOLOGY
  • 国际专利分类:   B01J027/24, B01J035/10, C02F001/30, C02F101/30
  • 专利详细信息:   CN115301267-A 08 Nov 2022 B01J-027/24 202304 Chinese
  • 申请详细信息:   CN115301267-A CN11047610 08 Sep 2021
  • 优先权号:   CN11047610

▎ 摘  要

NOVELTY - Preparing porous tubular carbon nitride catalyst comprises (1) adding melamine and cyanuric acid into deionized water, and magnetically stirring after ultrasonication at 20-28℃ to obtain mixed solution, (2) adding the mixed solution into hydrothermal reaction kettle and placing in oil bath with magnetic stirring, reacting at 120-200℃ for 8-12 hours, collecting the product by centrifugation, washing thoroughly, and drying at 55-65℃ to obtain the precursor, and (3) placing the precursor in ceramic crucible with lid and placing it in tube furnace, introducing nitrogen, raising the temperature to 450-650℃ at 2-5℃/minutes and keeping for 4-6 hours, and obtaining the porous tubular carbon nitride catalyst (HNCN) after natural cooling. USE - The catalyst is useful in visible light catalytic degradation of antibiotic pollutants (claimed). ADVANTAGE - The method: has simple process, strong operability and easy realization of industrialized production; has porous tubular morphology which can improve the visible light utilization efficiency of the catalyst; improves the electron transport performance; increases the specific surface area of graphene-like carbon nitride (g-C3N4); and improves the visible light catalytic performance of the catalyst. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for porous tubular carbon nitride catalyst (HNCN) prepared by the above-mentioned preparation method.