• 专利标题:   Preparing 3, 4-methylcyclohexylamine, involves introducing hydrogen, mixing 3, 4-dimethylaniline, ethylene glycol and ruthenium alloy catalyst to form mixture, reacting and under specific pressure, and stopping the reaction.
  • 专利号:   CN114560776-A
  • 发明人:   YANG Q, ZHONG H, GENG J, TIAN Y, CHEN X
  • 专利权人:   SHAOXING BSM CHEM CO LTD
  • 国际专利分类:   B01J023/89, B01J035/08, C07C209/72, C07C211/35
  • 专利详细信息:   CN114560776-A 31 May 2022 C07C-209/72 202284 Chinese
  • 申请详细信息:   CN114560776-A CN10273328 18 Mar 2022
  • 优先权号:   CN10273328

▎ 摘  要

NOVELTY - Preparing 3, 4-methylcyclohexylamine, involves introducing hydrogen, mixing 3, 4-dimethylaniline, ethylene glycol and a ruthenium alloy catalyst to form a mixture, reacting for 4-10 hours at 140-170℃ and under the pressure of 1.9-2.2 MPa, and stopping the reaction. When the concentration of the 3, 4-dimethylaniline in the mixture is lower than 1 wt.%, cooled to 30-50 ℃, and performed suction filtration and distillation to obtain the 3, 4-methylcyclohexylamine. USE - Method for preparing 3, 4-methylcyclohexylamine. ADVANTAGE - The preparation method is efficient and simple, has lower reaction temperature and high product yield, and is suitable for large-scale production.