• 专利标题:   Iron-based complex oxide/graphene composite material for use as cathode material of lithium ion battery, comprises laminated structure comprising nanoscale iron-based complex oxide and graphene.
  • 专利号:   CN102779994-A
  • 发明人:   CAO G, LIU S, SONG W, XIE J, ZHU T, ZHAO X, ZHENG Y
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   H01M004/52, H01M004/583
  • 专利详细信息:   CN102779994-A 14 Nov 2012 H01M-004/52 201342 Pages: 9 Chinese
  • 申请详细信息:   CN102779994-A CN10254510 23 Jul 2012
  • 优先权号:   CN10254510

▎ 摘  要

NOVELTY - An iron-based complex oxide/graphene composite material comprises a laminated structure comprising nanoscale iron-based complex oxide and graphene. USE - Iron-based complex oxide/graphene composite material for use as cathode material of lithium ion battery (Claimed). ADVANTAGE - The material is prepared with improved cycling stability and low energy consumption in a simple, inexpensive and rapid manner. DETAILED DESCRIPTION - An iron-based complex oxide/graphene composite material comprises a laminated structure comprising nanoscale iron-based complex oxide (MFe2O4) and graphene, where the M is manganese, copper, cobalt or nickel. An INDEPENDENT CLAIM is also included for a method for preparing iron-based complex oxide/graphene composite material, which involves dissolving trivalent iron salt and second M salt at a ratio of 2:1 in de-ionized water or organic solvent to obtain mixed solution (0.015-0.15 mol/l), dispersing graphene oxide (1-35%) of the iron-based complex oxide (MFe2O4) in the mixed solution ultrasonically to obtain mixture, where the M is manganese, copper, cobalt or nickel, followed by adding alkaline regulator to the mixture to adjust pH of the mixture to 8-9.5, sealing the resultant mixture, raising temperature to 190-280 degrees C to perform reaction for 22-48 hours to obtain a reaction product, cooling the reaction product to obtain a solid product, washing the solid product using with de-ionized water and absolute ethyl alcohol and drying the washed product to obtain finished product.