• 专利标题:   Forming metal-alloy graphene nanocomposite, used as electrocatalyst in fuel cell applications, comprises e.g. forming conducting polymer layer on surface of graphene substrate, and pyrolyzing layer to form nitrogen-doped graphene substrate.
  • 专利号:   WO2013160719-A1, WO2013160719-A8, US2015200403-A1, IN201201646-I4, US9847534-B2
  • 发明人:   SUNDARA R, PARAMBATH V B, NAGAR R, NATARAJAN R, VINAYAN B P
  • 专利权人:   INDIAN INST TECHNOLOGY MADRAS, INDIAN INST TECHNOLOGY MADRAS, SUNDARA R, PARAMBATH V B, NAGAR R, NATARAJAN R
  • 国际专利分类:   C01B031/00, C01B031/02, B05D001/38, B05D003/02, B05D007/00, H01M004/86, H01M004/88, H01M004/90, H01M004/92, B82Y010/00, B01J023/42, B01J031/18, C01B031/04, C22C019/00, C22C019/03, C22C019/07, C22C005/04, H01M008/1018
  • 专利详细信息:   WO2013160719-A1 31 Oct 2013 C01B-031/00 201376 Pages: 36 English
  • 申请详细信息:   WO2013160719-A1 WOIB001523 08 Aug 2012
  • 优先权号:   INCH01646

▎ 摘  要

NOVELTY - Method (M1) of forming a metal-alloy graphene nanocomposite (218), comprises: providing a graphene substrate; forming a conducting polymer layer (210) on a first major surface of the graphene substrate; pyrolyzing the conducting polymer layer to form a nitrogen-doped graphene substrate (212); and dispersing many metal-alloy nanoparticles (214) on a first surface (216) of the nitrogen-doped graphene substrate to form the nanocomposite. USE - The method is useful for forming a metal-alloy graphene nanocomposite which is useful as an electrocatalyst in a proton exchange membrane fuel cell, where the electrocatalyst is configured as an electrode of a proton exchange membrane fuel cell (all claimed), and the fuel cells are useful in an automotive and mobile applications. ADVANTAGE - The method provides electrocatalyst in a simple and cost-effective manner and in a non-toxic process. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) a metal-alloy graphene nanocomposite comprising: a nitrogen-doped graphene substrate; and many metal-alloy nanoparticles dispersed on a first major surface of the nitrogen-doped graphene substrate; (2) an electrocatalyst, comprising: a nitrogen-doped graphene substrate; and many platinum-cobalt alloy nanoparticles dispersed on a first major surface of the nitrogen-doped graphene substrate; and (3) an electrocatalyst formed (M2) by providing a nitrogen-doped graphene substrate and dispersing many platinum-cobalt alloy nanoparticles on a first surface of the nitrogen-doped graphene substrate. DESCRIPTION OF DRAWING(S) - The figure illustrates materials and/or compositions used/formed at different stages of forming a metal-alloy graphene nanocomposite. Conducting polymer layer (210) Nitrogen-doped graphene substrate (212) Metal-alloy nanoparticles (214) First surface of nitrogen-doped graphene substrate (216) Metal-alloy graphene nanocomposite (218)