• 专利标题:   Preparation of composite catalyst of graphene oxide and cerium-based metal-organic framework for adsorbing and degrading sulfamethoxazole, involves dripping mixed solution of graphene oxide and ceric ammonium nitrate into terephthalic acid solution, heating, centrifuging, washing, and drying.
  • 专利号:   CN115814860-A
  • 发明人:   XIN B, MI X, FENG X, WANG B, LI X
  • 专利权人:   BEIJING INST TECHNOLOGY, BEIJING TECHNOLOGY TANGSHAN RES INST
  • 国际专利分类:   B01J031/22, C02F001/30, C02F101/34, C02F101/38
  • 专利详细信息:   CN115814860-A 21 Mar 2023 B01J-031/22 202330 Chinese
  • 申请详细信息:   CN115814860-A CN10106970 14 Feb 2023
  • 优先权号:   CN10106970

▎ 摘  要

NOVELTY - Preparation of composite catalyst of graphene oxide (GO) and cerium-based metal-organic frameworks (MOFs) involves (S1) mixing graphene oxide with ceric ammonium nitrate uniformly, (S2) dripping the uniformly mixed solution into a terephthalic acid solution, stirring while heating, and centrifuging to obtain white precipitate after the reaction, and (S3) washing the white precipitate with dimethyl formamide (DMF) and ethanol, and drying the washed product. USE - Preparation of composite catalyst of graphene oxide and cerium-based metal-organic framework for adsorbing and degrading antibiotics e.g. sulfamethoxazole in sulfamethoxazole-containing wastewater (all claimed). ADVANTAGE - The method provides composite catalyst having improved kinetic performance due to its kinetic constant of more than 3 times that of UIO-66(Ce) and GO before composite, and ensures degradation of 78% of sulfamethoxazole within 240 minutes, thus ensuring effective removal of antibiotics in water. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for usage method of the composite catalyst, which involves adding the composite catalyst into wastewater containing sulfamethoxazole, and adsorbing and degrading sulfamethoxazole under visible light conditions.