• 专利标题:   Adhesive used in lithium ion battery negative electrode material, comprises modified polyethyleneimine comprising dopaic acid and/or unsaturated hydroxy fatty acid.
  • 专利号:   CN113571709-A, CN113571709-B, WO2023005520-A1
  • 发明人:   HE H, CHEN K, SHEN Z, FENG Y, LI Z
  • 专利权人:   SUZHOU QINGTAO NEW ENERGY TECHNOLOGY CO, SUZHOU QINGTAO NEW ENERGY S T CO LTD
  • 国际专利分类:   C08G073/02, H01M010/0525, H01M004/62
  • 专利详细信息:   CN113571709-A 29 Oct 2021 H01M-004/62 202234 Chinese
  • 申请详细信息:   CN113571709-A CN10860499 28 Jul 2021
  • 优先权号:   CN10860499

▎ 摘  要

NOVELTY - Adhesive comprises modified polyethyleneimine comprising a combination of dopaic acid and/or unsaturated hydroxy fatty acid. USE - The adhesive is used in a lithium ion battery negative electrode material (claimed). ADVANTAGE - The adhesive has excellent flexibility and strong bonding ability with silicon, has improved drying rate, crack resistance, rate performance and cycle performance of the pole piece. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a method for preparing the adhesive comprising (a) method A or method B, where the method (A) involves reacting polyethyleneimine, dobaic acid, and unsaturated hydroxy fatty acid to obtain the binder, and the method B involves (i) reacting polyethyleneimine with dopaic acid to obtain dopaic acid-modified polyethyleneimine, (ii) reacting the dopaic acid-modified polyethyleneimine obtained in step (i) with unsaturated hydroxy fatty acid to obtain the binder; and (2) a lithium ion battery negative electrode material comprises a negative electrode active material, a conductive agent, and the adhesive, the negative active material is a silicon-based active material, 94-98 %mass negative electrode active material, and 1-5 %mass conductive agent, 0.5-1.5 %mass negative electrode material, the silicon-based active material comprises at least two of elemental silicon, silicon alloy, silicon-carbon compound, or silicon-oxygen compound, and the conductive comprises acetylene black, Ketjen black, carbon fiber, superconducting carbon black, carbon nanotube, and graphene.