• 专利标题:   Three dimensional printing cellulose/nano-inorganic filler composite gel ink useful in electronic devices and electronic packaging, comprises a cellulose-based composite gel aqueous solution with nano-inorganic materials and cellulose.
  • 专利号:   CN112812376-A
  • 发明人:   SONG N, WANG P, DING P
  • 专利权人:   UNIV SHANGHAI
  • 国际专利分类:   B33Y070/10, C08J003/075, C08J003/24, C08K003/04, C08K003/34, C08K005/1515, C08K007/00, C08L001/02
  • 专利详细信息:   CN112812376-A 18 May 2021 C08L-001/02 202149 Pages: 10 Chinese
  • 申请详细信息:   CN112812376-A CN10041961 13 Jan 2021
  • 优先权号:   CN10041961

▎ 摘  要

NOVELTY - Three dimensional printing cellulose/nano-inorganic filler composite gel ink, comprises a cellulose-based composite gel aqueous solution with nano-inorganic materials as fillers and cellulose as a polymer matrix, i.e. 15-20 pts. wt. nano-inorganic filler dispersion, 90-100 pts. wt. cellulose dispersion, and 1-2 pts. wt. chemical crosslinking agent. The addition amount of nano-inorganic filler in the nano-inorganic filler dispersion is 0.5-30 wt.%, and the addition amount of fiber in the cellulose dispersion is 4-6 wt.%. USE - The polymer-reinforced composite material is useful in electronic devices and electronic packaging. ADVANTAGE - The method is efficient, the prepared gel ink has good biocompatibility, mechanical properties and environmental friendliness, and the polymer matrix has a wide range of sources and low raw material costs. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the 3D printing cellulose/nano-inorganic filler composite gel ink, comprising (i) adding a quantitative amount of nano-inorganic filler into deionized water, and ultrasonically dispersing to obtain a uniformly dispersed nano-inorganic filler dispersion; (ii) pre-cooling quantitative amount of cotton linters, adding the alkali/urea solution to a specified temperature, and stirring quickly to obtain a cellulose dispersion; adding the nano-inorganic filler dispersion to the cellulose, stirring vigorously in the dispersion to obtain a mixed dispersion of cellulose/nano-inorganic filler; (iii) stirring mixed dispersion of cellulose/nano-inorganic filler vigorously under a set temperature, and slowly adding chemical cross-linking agent dropwise to make it partially cross-linked, and removing the mixed dispersion by centrifugation, allowing the air bubbles in the liquid to stand still under a set temperature condition to obtain a partially cross-linked 3D printing cellulose/nano-inorganic filler composite gel-like ink.