• 专利标题:   Composite of graphene and Congo red for industrial and commercial applications comprises two soluble phases.
  • 专利号:   CN101698476-A, CN101698476-B
  • 发明人:   BAO Y, DENG P, LI F, NIU L, WANG X, ZHANG Q
  • 专利权人:   CHANGCHUN APPLIED CHEM INST CHINESE ACAD, CHINESE ACAD SCI CHANGCHUN INST APPL CHE
  • 国际专利分类:   C01B031/00, C01B031/04
  • 专利详细信息:   CN101698476-A 28 Apr 2010 C01B-031/00 201032 Pages: 10 Chinese
  • 申请详细信息:   CN101698476-A CN10217850 13 Nov 2009
  • 优先权号:   CN10217850

▎ 摘  要

NOVELTY - Composite of graphene and Congo red comprises two soluble phases, where the mass ratio of graphene to Congo red is 5:1-10. USE - The composite of graphene and Congo red is useful for industrial and commercial applications. ADVANTAGE - The maximum solubility of the composite in water is 7.5 mg/ml and it can stably exist for more than 3 months. The solubility of the composite in solution of N, N-dimethyl formamide is 2 mg/ml and it can stably exist for 2-3 weeks. The composite supplies ideal graphene material for practical application. DETAILED DESCRIPTION - Composite of graphene and Congo red of Formula (I) comprises two soluble phases, where the mass ratio of graphene to Congo red is 5:1-10. An INDEPENDENT CLAIM is a preparation method for composite of graphene and Congo red with two soluble phases comprising: (a) preparing graphene: mixing water solution of graphene oxide having a concentration of 0.5 mg/ml, hydrazine hydrate solution having a mass fraction of 50% and ammonia water solution having a mass fraction of 25% in a reactor; mass ratio of graphene oxide, hydrazine to ammonia is 10: 7-35: 35-175; stirring and reacting them for 0.5-1 hour in oil bath of 80-110 degrees C; obtaining solution of graphene; and (b) preparing composite of graphene and Congo red: adding Congo red in the solution of graphene obtained in step (a) according to mass ratio of graphene to Congo red of 5:1-10; stirring and reacting them for 10-48 hours in oil bath of 30-60 degrees C; cooling them to 20-25 degrees C; filtering them by using nylon film of 0.22 micron; washing them twice with water until the filtrate is colorless; then obtaining composite of graphene and Congo red with two soluble phases.