• 专利标题:   Preparation of ruthenium-nickel/reduced graphene oxide-mixed metal oxide (rGO-MMO) aerogel catalyst for purification of carbon monoxide selective methanation in hydrogen-rich gas, by soaking rGO-MMO aerogel in ruthenium chloride solution.
  • 专利号:   CN113398935-A, CN113398935-B
  • 发明人:   DONG X, FENG J, GENG J
  • 专利权人:   UNIV SOUTH CHINA TECHNOLOGY
  • 国际专利分类:   B01J023/755, B01J023/89, B01J032/00, B01J035/00, C01B003/58
  • 专利详细信息:   CN113398935-A 17 Sep 2021 B01J-023/755 202192 Pages: 12 Chinese
  • 申请详细信息:   CN113398935-A CN10575256 26 May 2021
  • 优先权号:   CN10575256

▎ 摘  要

NOVELTY - Preparation of ruthenium-nickel/graphene-composite metal oxide aerogel catalyst comprises adding graphene oxide solution to stripping nickel aluminum hydrotalcite colloidal solution, ultrasonically dispersing, forming hydrogel through layer-by-layer self-assembly, freeze-drying, and calcining under inert atmosphere to obtain reduced graphene oxide-mixed metal oxide (rGO-MMO) aerogel, adding to ruthenium chloride solution, soaking, drying under air atmosphere, and subjecting to reduction under hydrogen-containing atmosphere. USE - The method is for preparation of ruthenium-nickel/graphene-composite metal oxide aerogel catalyst used for purification reaction of carbon monoxide selective methanation in hydrogen-rich gas (claimed). ADVANTAGE - The catalyst does not easily agglomerates, and has large specific surface area, high active metal dispersion, high activity and selectivity, and wide window of suitable operating temperature. The purified hydrogen-rich feed gas can meet the requirements of proton exchange membrane fuel cells for high-quality hydrogen sources. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a ruthenium-nickel/graphene-composite metal oxide aerogel catalyst.