• 专利标题:   Preparing silver/copper oxide/reduced graphene oxide nano composite antibacterial agent by e.g. obtaining graphene oxide suspension, preparing copper acetate-silver acetate solution, preparing silver ion/copper(II) ion/graphene oxide mixed solution, reacting, centrifuging and vacuum drying.
  • 专利号:   CN113881100-A, CN113881100-B
  • 发明人:   MA Z, ZHANG Y, ZHANG H, PAN D, XIAN L
  • 专利权人:   SHENZHEN QIANHAI GRAPHENE IND CO LTD, SHENZHEN HUANNENG GRAPHENE TECHNOLOGY CO
  • 国际专利分类:   C08J005/18, C08K003/04, C08K003/08, C08K003/22, C08L023/08
  • 专利详细信息:   CN113881100-A 04 Jan 2022 C08K-003/08 202220 Chinese
  • 申请详细信息:   CN113881100-A CN11121192 24 Sep 2021
  • 优先权号:   CN11121192

▎ 摘  要

NOVELTY - Preparing silver/copper oxide/reduced graphene oxide (Ag/Cu2O/rGO) nano composite antibacterial agent by (a) dispersing graphene oxide in glycol solvent, magnetic stirring to obtain the graphene oxide suspension; (b) adding copper acetate and silver acetate in glycol, stirring and dissolving to obtain copper acetate-silver acetate solution; (c) dropping copper acetate-silver acetate glycol solution in graphene oxide suspension, magnetically stirring and ultrasonically processing at room temperature, obtaining silver ion/copper(II) ion/graphene oxide (Ag+/Cu2+/GO) mixed solution; (d) transferring Ag+/Cu2+/GO mixed solution to the polytetrafluoroethylene lined stainless steel high pressure reaction kettle, sealing, placing into an electric heating constant temperature drying box to react for 6-24 hours at 150-200degrees Celsius; and (e) naturally cooling to room temperature, centrifuging sample, using de-ionized water and ethanol to wash for 2-4 times, placing in a vacuum drying box to dry. USE - Preparing silver/copper oxide/reduced graphene oxide (Ag/Cu2O/rGO) nano composite antibacterial agent ADVANTAGE - The method solves the problems of poor antibacterial property, durability and high cost of Ag/rGO composite materials. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) Ag/Cu2O/rGO nano-composite antibacterial agent prepared directly by the method; (2) Ag/Cu2O/rGO nano-composite antibacterial master batch prepared by mixing Ag/Cu2O/rGO nano-composite antibacterial agent and ethylene vinyl alcohol (EVOH) resin; and (3) Preparation of Ag/Cu2O/rGO nanocomposite antibacterial master batch comprising adding Ag/Cu2O/rGO composite antibacterial agent and EVOH resin according to the mass ratio of 3-5:100, adding in double-screw extruder to blend, granulating, finishing primary granulation, adding the particles after primary granulation into a single-screw extruder for secondary granulation to obtain the master batch.