• 专利标题:   Preparing graphene encapsulation non-noble metal hydrogen evolution electro-catalyst comprises e.g. preparing titanium-doped nickel molybdate, calcining titanium-doped nickel molybdate in inert gas/hydrogen mixed atmosphere, growing graphene encapsulation layer, and cooling to room temperature.
  • 专利号:   CN115747864-A
  • 发明人:   LIN X, CHEN Y, CAI Z, HU K
  • 专利权人:   HARBIN INST TECHNOLOGY SHENZHEN GRADUATE
  • 国际专利分类:   C25B001/04, C25B011/065, C25B011/091, C25B009/19
  • 专利详细信息:   CN115747864-A 07 Mar 2023 C25B-011/091 202323 Chinese
  • 申请详细信息:   CN115747864-A CN11277489 19 Oct 2022
  • 优先权号:   CN11277489

▎ 摘  要

NOVELTY - Preparing graphene encapsulation non-noble metal hydrogen evolution electro-catalyst comprises (i) preparing titanium-doped nickel molybdate, where the mass percentage of titanium doping is 0.1-5%, (ii) calcining titanium-doped nickel molybdate at 800-850℃ for 1-60 minutes in an inert gas/hydrogen mixed atmosphere to obtain nickel molybdenum alloy, and (iii) cooling to 700-750℃, injecting pyridine steam for 1 seconds-2 minutes, and growing a graphene encapsulation layer, stop heating, cooling to room temperature to obtain graphene encapsulation titanium-doped nickel molybdenum alloy material. The inert gas is argon gas, helium gas or neon gas. USE - The method is useful for preparing graphene encapsulation non-noble metal hydrogen evolution electro-catalyst. ADVANTAGE - The catalyst has good hydrogen evolution catalytic activity, and better catalytic stability, improves capability of resisting acid corrosion, catalyzes HER reaction in the acidic environment, and is economical. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for graphene encapsulation non-noble metal hydrogen evolution electro-catalyst.