• 专利标题:   Preparation of graphene-based anticorrosive paint involves adding epoxy resin E-51, thinner, ground mica iron oxide and ground superfine talcum powder, mixing, adding floating aluminum powder slurry and precipitated barium sulfate, mixing, adding modified graphene and dispersant, and dispersing.
  • 专利号:   CN115247020-A
  • 发明人:   WANG M, XU X, SONG F, SONG J, SONG L, SONG Z
  • 专利权人:   HEBEI SILICON VALLEY CHEM CO LTD, HEBEI SILICON VALLEY CHEM CO LTD
  • 国际专利分类:   C09D163/02, C09D005/10, C09D007/61, C09D007/62
  • 专利详细信息:   CN115247020-A 28 Oct 2022 C09D-163/02 202301 Chinese
  • 申请详细信息:   CN115247020-A CN10446002 25 Apr 2021
  • 优先权号:   CN10446002

▎ 摘  要

NOVELTY - Preparation of graphene-based anticorrosive paint involves reducing graphene, adding a stabilizer, performing π-π interaction to obtain dispersed and stable graphene nanosheets, hydrogenating, fluorinating, halogenating, introducing free radicals or benzene rings into the graphene and modifying to obtain a modified graphene, adding epoxy resin E-51, thinner, ground mica iron oxide and ground superfine talcum powder to a high-speed stirrer, stirring and mixing well to obtain a mixed slurry for later use, adding floating aluminum powder slurry and precipitated barium sulfate to the mixed slurry and stirring with a high-speed stirrer to obtain a paint, adding the modified graphene, the dispersant and the paint to a high-speed disperser and dispersing at a speed of 1200 rpm, so that the modified graphene can be uniformly dispersed in the paint to obtain an anticorrosive paint, and packaging the anticorrosive paint according to the specifications. USE - Preparation of graphene-based anticorrosive paint. ADVANTAGE - The graphene-based anticorrosive paint is hydrophobic. By modifying graphene, the solubility, dispersibility and compatibility of graphene inorganic nanofillers in the coating matrix are effectively improved, while maintaining its performance, and without destroying the conjugated structure of graphene. By adding modified graphene to the paint, the graphene can be completely dispersed in the paint, enhance the overall performance of the paint, make the paint highly anticorrosive and make the paint work better. DETAILED DESCRIPTION - Preparation of graphene-based anticorrosive paint involves (i) selecting raw materials comprising 20-30% epoxy resin E-51, 5-15% thinner, 0.5% dispersant, 10-20% mica iron oxide, 10-20% superfine talcum powder, 1% floating aluminum powder slurry, 1-5% graphene and 10-20% precipitated barium sulfate, (ii) reducing graphene, adding a stabilizer to the reduced graphene, performing π-π interaction between the stabilizer and graphene to obtain dispersed and stable graphene nanosheets, hydrogenating, fluorinating, halogenating, introducing free radicals or benzene rings into the graphene, modifying covalent bonds and non-covalent bonds to realize the surface functionalization of graphene, realize the pre-wetting of graphene by the stabilizer, and effectively improve the solubility, dispersion and phase properties of graphene inorganic nanofillers in the coating matrix, while maintaining its performance, and without destroying the conjugated structure of graphene, to obtain a modified graphene, (iii) grinding mica iron oxide and superfine talcum powder in a grinder, (iv) adding the epoxy resin E-51, thinner, ground mica iron oxide and ground superfine talcum powder to a high-speed stirrer, stirring and mixing well to obtain a mixed slurry for later use, (v) adding floating aluminum powder slurry and precipitated barium sulfate to the mixed slurry and stirring with a high-speed stirrer to obtain a paint, (vi) adding the modified graphene, the dispersant and the paint to a high-speed disperser and dispersing at a speed of 1200 rpm, so that the modified graphene can be uniformly dispersed in the paint to obtain an anticorrosive paint, and (viii) packaging the anticorrosive paint according to the specifications.