• 专利标题:   Preparation of polyvinylidene fluoride-ethylene thermally-conductive composite material involves adding polyvinylidene fluoride and carbon nanotubes to graphene oxide/N,N-dimethylformamide solution, and heating mixture.
  • 专利号:   CN104530615-A, CN104530615-B
  • 发明人:   HUANG T, WANG Y, YANG J, ZHANG N, ZHANG W
  • 专利权人:   UNIV SOUTHWEST JIAOTONG
  • 国际专利分类:   C08K003/04, C08K007/24, C08K009/04, C08L027/16
  • 专利详细信息:   CN104530615-A 22 Apr 2015 C08L-027/16 201545 Pages: 8 Chinese
  • 申请详细信息:   CN104530615-A CN10837385 30 Dec 2014
  • 优先权号:   CN10837385

▎ 摘  要

NOVELTY - A graphene oxide/N,N-dimethylformamide solution is prepared by dissolving 25-50 %mass dilute aqueous solution of graphite oxide in N,N-dimethylformamide and distilling under reduced pressure. After completion of distillation, the distillate is ultrasonically-treated. Polyvinylidene fluoride and carbon nanotubes are added to distillate, and magnetic-stirred, to obtain a mixture (m1). The mixture (m1) is ultrasonically treated and heated at 100-120 degrees C, to obtain viscous liquid. The viscous liquid is oven-dried, to obtain a polyvinylidene fluoride-ethylene thermally-conductive composite material. USE - Preparation of polyvinylidene fluoride-ethylene thermally-conductive composite material (claimed). ADVANTAGE - The method enables preparation of polyvinylidene fluoride-ethylene composite material having excellent thermal conductivity and mechanical property. DETAILED DESCRIPTION - A graphene oxide/N,N-dimethylformamide solution is prepared by dissolving 25-50 %mass dilute aqueous solution of graphite oxide in N,N-dimethylformamide and distilling under reduced pressure. The volume ratio of graphene oxide and aqueous solution of N,N-dimethylformamide is 2:1. After completion of distillation, the distillate is ultrasonically-treated. Polyvinylidene fluoride and carbon nanotubes are added to distillate, and magnetic-stirred at 80-90 degrees C for 3-6 hours, to obtain a mixture (m1). The mass ratio of polyvinylidene fluoride, carbon nanotubes and graphene oxide is 80-90:5-15:1-5. The mixture (m1) is ultrasonically treated at 80-90 degrees C and heated at 100-120 degrees C, to obtain viscous liquid. The viscous liquid is oven-dried at 50-80 degrees C, to obtain a polyvinylidene fluoride-ethylene thermally-conductive composite material.