• 专利标题:   Polyimide self-lubricating ink useful as 3D printing ink in self-lubricating molded device for direct writing 3D printing, comprises polyamic acid, organic solvent, thickener and self-lubricating agent.
  • 专利号:   CN112898772-A, CN112898772-B
  • 发明人:   WANG X, QIN S, GUO Y, JIANG P, ZHOU F
  • 专利权人:   LANZHOU CHEM PHYSICS INST CHINESE ACAD
  • 国际专利分类:   B33Y070/10, C08K003/04, C08K003/22, C08K003/30, C08K007/18, C08L001/04, C08L079/08
  • 专利详细信息:   CN112898772-A 04 Jun 2021 C08L-079/08 202153 Pages: 9 Chinese
  • 申请详细信息:   CN112898772-A CN11132463 19 Nov 2019
  • 优先权号:   CN11132463

▎ 摘  要

NOVELTY - Polyimide self-lubricating ink comprises 20-70 pts. wt. polyamic acid, 30-60 pts. wt. organic solvent, 1-10 pts. wt. thickener and 1-20 pts. wt. self-lubricating agent. The number average molecular weight of the polyamic acid is 5000-500,000. The viscosity of the polyimide self-lubricating ink is 102-105 Pa/s. USE - The polyimide self-lubricating ink is useful as 3D printing ink in self-lubricating molded device for direct writing 3D printing (claimed). ADVANTAGE - The ink: has low friction coefficient and wear rate, excellent thermal stability, high precision, excellent dimensional stability, corrosion resistance and high mechanical strength; and can realizes the designability, customizability and complexity of self-lubricating molded devices. The method: has simple process, low cost and low energy consumption. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) preparing polyimide self-lubricating ink, comprising mixing polyamic acid, organic solvent, thickener and self-lubricating agent, then carrying out ultrasonication and ball milling to obtain mixture, and then degassing the mixture to obtain polyimide self-lubricating ink; and (2) use method of polyimide self-lubricating ink as 3D printing ink in direct writing 3D printing, comprising printing polyimide self-lubricating ink after establishing a model through direct writing 3D printer to obtain blank, and then heating the blank for imidization to obtain self-lubricating molded device.