• 专利标题:   Anti-ozone rubber sole comprises butadiene rubber, styrene-butadiene rubber, natural rubber, graphene oxide, white carbon black, rubber powder, liquid polyisobutene, zinc oxide, petroleum resin, polyethylene glycol, and coupling agent.
  • 专利号:   CN110982132-A
  • 发明人:   ZHANG Q, LU X
  • 专利权人:   ZHEJIANG HENGCHENG SHOE IND CO LTD
  • 国际专利分类:   A43B013/04, C08K013/06, C08K003/04, C08K009/02, C08K009/04, C08L023/20, C08L057/02, C08L007/00, C08L009/00, C08L009/06
  • 专利详细信息:   CN110982132-A 10 Apr 2020 C08L-009/00 202037 Pages: 12 Chinese
  • 申请详细信息:   CN110982132-A CN11113060 14 Nov 2019
  • 优先权号:   CN11113060

▎ 摘  要

NOVELTY - Anti-ozone rubber sole comprises 24 pts. wt. butadiene rubber, 16-20 pts. wt. styrene-butadiene rubber, 8-12 pts. wt. natural rubber, 5-10 pts. wt. graphene oxide, 20 pts. wt. white carbon black, 5 pts. wt. rubber powder, 2 pts. wt. liquid polyisobutene, 2 pts. wt. zinc oxide, 1.5 pts. wt. petroleum resin, 1.3 pts. wt. polyethylene glycol, 1.3 pts. wt. coupling agent, 0.3 pts. wt. polyethylene wax, 0.4 pts. wt. stearic acid, 0.1 pts. wt. antioxidant, 0.8 pts. wt. vulcanization accelerator DM (2'-dibenzothiazole Disulfide), 1.4 pts. wt. insoluble sulfur, and 0.2 pts. wt. vulcanization accelerator NS (1,3-diphenylguanidine). USE - Anti-ozone rubber sole. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing anti-ozone rubber sole, which involves: (A) placing butadiene rubber, solution polystyrene-butadiene rubber, and natural rubber into the internal mixer, smelting for 2 minutes, and then the intercalating graphene oxide, white carbon black, rubber powder, liquid polyisobutylene, and pouring in internal mixer, kneading for 2 minutes, opening the input door of the internal mixer, pouring zinc oxide, petroleum resin, polyethylene glycol, coupling agent, polyethylene wax, stearic acid, antioxidant, vulcanization accelerator into the internal mixer, turning the material 8 times, discharging the glue at 113-116 degrees C, and immediately delivering to the open mixer; (B) transporting and dumping the materials on the wheel table of the open mill, where the temperature of the open mill is 65-75 degrees C, the roller wheel distance is adjusted to 6 mm, and the tablet falls after mixing into the tray; (C) adjusting the other direction, pushing nto the wheel table, mixing and heating the triangle bag 3 times, then pressing the tablet and falling into the tray, adjusting roller wheel distance to 3 mm, discharging mixed rubber material from the film, soaking through the cooling pool, the cooling water temperature is 0-5 degrees C, and then passing through the slicer to obtain a width of 44-46 cm and a length of 115-125cm rubber compound; (D) pouring rubber compound on the wheel table of a double-roll mill, the temperature of the mill is 55-70 degrees C, adjusting roller wheel distance to 6 mm, and mixing rubber 4 times, and adding insoluble sulfur and vulcanization accelerator NS to the material, and mixing triangle bag is mixed for 5 times, and then compressing and dropping into the material tray, adjusting roller wheel distance to 3 mm, and the taking out mixed rubber material of the sheet, soaking in the cooling pool, the cooling water temperature is 0-5 degrees C, and then soaking in the anti-adhesive suspension sink to obtain the rubber sheet to be vulcanized; and (E) transferring rubber sheet to be vulcanized to obtain a rubber sheet to be vulcanized in the shape of a shoe sole, heating, setting at temperature 160-165 degrees C, time 160-280 seconds, at pressure of 120-150 bar, pulling out and opening the mold, pulling the product out of the mold and placing on the inspection platform, eliminating unqualified sole, trimming qualified sole and sorting to obtain final product.