• 专利标题:   Graphene oxide-doped polyvinyl chloride basic anion exchange polymer film used in electrochemical energy device, comprises water-soluble polyvinyl alcohol containing hydroxyl groups, poly diallyl dimethyl ammonium chloride containing quaternary ammonium groups and graphene oxide.
  • 专利号:   CN114736475-A
  • 发明人:   CHEN J, LU T, DONG X, NIU Z, ZOU Q, QIAO J
  • 专利权人:   UNIV DONGHUA
  • 国际专利分类:   C08J005/22, C08K003/04, C08L029/04, C08L039/02, C25B013/08, C25B003/07, C25B003/26, H01M012/08, H01M050/414
  • 专利详细信息:   CN114736475-A 12 Jul 2022 C08L-029/04 202278 Chinese
  • 申请详细信息:   CN114736475-A CN10273121 19 Mar 2022
  • 优先权号:   CN10273121

▎ 摘  要

NOVELTY - Graphene oxide-doped polyvinyl chloride (PVA) basic anion exchange polymer film comprises water-soluble polyvinyl alcohol (PVA) containing hydroxyl groups, poly diallyl dimethyl ammonium chloride containing quaternary ammonium groups and graphene oxide. USE - Graphene oxide-doped polyvinyl chloride basic anion exchange polymer film used in electrochemical energy device, which is a carbon dioxide electrochemical reduction reactor or metal-air battery (claimed). ADVANTAGE - The graphene oxide doped PVA basic anion exchange polymer film has good conductivity, high chemical stability, simple and mild process, low carbon and environment-friendly raw material, low cost and easy for electrochemical device application. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing the graphene oxide doped PVA-based basic anion exchange polymer film, which involves: (1) dissolving graphene oxide in deionized water, and performing ultrasonic dispersion at normal temperature to obtain a fully and uniformly mixed solution A; (2) dissolving water-soluble PVA containing hydroxyl in deionized water, heating in a water bath at 80-95℃, and stirring until the mixture is uniform and transparent to obtain a solution B; and slowly adding the solution of poly (diallyldimethylammonium chloride) containing quaternary ammonium groups into the solution B, and stirring to obtain a uniform and transparent solution C; and mixing solution A and solution C, and continuously stirring the mixture until the mixture is uniform, and casting the mixture into a culture dish, and naturally drying the mixture to form a film; and (3) peeling the film prepared from the culture dish, and sequentially performing physical and chemical crosslinking, and finally soaking in a potassium hydroxide (KOH) solution for ion exchange.