• 专利标题:   Self-repairing dielectric composite material comprises self-repairing linear polyurethane, multi-walled carbon nanotubes, graphene oxide and N,N-dimethylformamide.
  • 专利号:   CN107974072-A
  • 发明人:   ZHANG G, LING L, SUN R
  • 专利权人:   SHENZHEN INST ADVANCED TECHNOLOGY
  • 国际专利分类:   C08L075/08, C08K007/24, C08K003/04, C08G018/76, C08G018/48, C08G018/38, C08G018/10
  • 专利详细信息:   CN107974072-A 01 May 2018 C08L-075/08 201837 Pages: 9 Chinese
  • 申请详细信息:   CN107974072-A CN11249280 01 Dec 2017
  • 优先权号:   CN11249280

▎ 摘  要

NOVELTY - Self-repairing dielectric composite material comprises self-repairing linear polyurethane, multi-walled carbon nanotubes, graphene oxide and N,N-dimethylformamide. USE - Used as self-repairing dielectric composite material. ADVANTAGE - The self-repairing dielectric composite material has good mechanical performance, high dielectric constant and low dielectric loss and can achieve high-efficiency self-repair while heating after mechanical damage. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing dielectric composite material, comprising (i) dissolving 4,4'-methylenebis(phenyl isocyanate) and polytetrahydrofuran in N,N-dimethylformamide solvent to obtain 4,4'-methylenebis(phenylisocyanate) solution and polytetrahydrofuran solution; (ii) reacting 4,4'-methylenebis(phenyl isocyanate) solution and polytetrahydrofuran solution under inert gas protection; (iii) dissolving bis(4-hydroxyphenyl)disulfide in N,N-dimethylformamide solvent to obtain bis(4-hydroxyphenyl) disulfide solution, adding bis (4-hydroxyphenyl) disulfide solution to reactant obtained in step (ii) to obtain self-repairing linear polyurethane; (iv) dispersing multi-walled carbon nanotubes and graphene oxide respectively in N,N-dimethylformamide solvent to form multi-walled carbon nanotube suspension and graphene oxide suspension respectively; (v) mixing multi-walled carbon nanotube suspension and graphene oxide suspension, dispersing mixture by ultrasonic waves, and adding to self-repaired linear polyurethane for melt blending; (vi) adding reducing agent to system after melt blending in step (v), adding solvent to the system and drying to obtain reaction product; (vii) dissolving reaction product in N,N-dimethylformamide solvent to obtain reaction product solution; and (viii) pouring reaction product solution into a template and removing solvent in reaction product solution.