• 专利标题:   Preparation of coated nitrogen-doped graphene ternary material used as battery material, by taking ternary material precursor and lithium source, grinding, mixing, adding volatile solvent, blending, ball milling, stirring, and oven-drying.
  • 专利号:   CN107403918-A
  • 发明人:   JIANG Q, LI J, TANG J, CUI X, LI H, ZHANG X
  • 专利权人:   UNIV QINGDAO
  • 国际专利分类:   C01B032/194, H01M010/0525, H01M004/36, H01M004/505, H01M004/525, H01M004/583, H01M004/62
  • 专利详细信息:   CN107403918-A 28 Nov 2017 H01M-004/36 201783 Pages: 9 Chinese
  • 申请详细信息:   CN107403918-A CN10619872 26 Jul 2017
  • 优先权号:   CN10619872

▎ 摘  要

NOVELTY - Preparation of coated nitrogen-doped graphene ternary material by taking ternary material precursor and lithium source, grinding, and mixing uniformly to obtain sample; adding volatile solvent to sample to obtain second sample; adding second sample, blending in volatile solvent, and ball milling to obtain third sample; stirring third sample, and oven-drying at 80-100 degrees C for 6-10 hours to obtain dried sample; and putting dried sample to tubular furnace, introducing air or argon gas in tube furnace, heating tubular furnace uniformly, heating, and calcining to obtain ternary material. USE - Method for preparing coated nitrogen-doped graphene ternary material used as battery material (claimed). ADVANTAGE - The capacity retention rate is 3.54%. The synthesized coated nitrogen-doped graphene material has excellent cycle stability, and higher cycle capacity. The preparation has simple operation, and low cost. The material is suitable for industrial production, and environment-friendly. DETAILED DESCRIPTION - Preparation of coated nitrogen-doped graphene ternary material comprises taking ternary material precursor and lithium source, grinding, and mixing uniformly to obtain sample; adding volatile solvent to sample to obtain second sample; adding second sample, blending in volatile solvent, and ball milling to obtain third sample; stirring third sample, and oven-drying at 80-100 degrees C for 6-10 hours to obtain dried sample; putting dried sample to tubular furnace, introducing air or argon gas in tube furnace, heating tubular furnace uniformly, heating, and calcining to obtain ternary material; mixing graphene oxide to ternary material, adding water to dilute, and cell crushing to obtain prepared sample; and crushing sample, putting in tubular furnace, introducing ammonia gas, heating uniformly, calcining to obtain coated material of nitrogen-doped graphene, using ammonia gas, nitrogen-doping, and coating ternary material on graphene.