• 专利标题:   Surface modified hexagonal boron nitride particles used for thermally conductive resin composition, have partially reduced graphene oxide adsorption layer on surface of untreated hexagonal boron nitride particle.
  • 专利号:   JP2022144419-A
  • 发明人:   ZAIMA H, SUGIMORI S, ONAKA J, ITO G
  • 专利权人:   KRI INC
  • 国际专利分类:   C01B021/064, C01B032/198, C08K003/38, C09K005/14
  • 专利详细信息:   JP2022144419-A 03 Oct 2022 C01B-021/064 202289 Pages: 14 Japanese
  • 申请详细信息:   JP2022144419-A JP045422 19 Mar 2021
  • 优先权号:   JP045422

▎ 摘  要

NOVELTY - Surface modified hexagonal boron nitride particles have a partially reduced graphene oxide adsorption layer on the surface of the untreated hexagonal boron nitride particle, where the amount of the partially reduced graphene oxide adsorption layer is 1.5 times or more the amount of the graphene oxide adsorption layer of the surface-modified hexagonal boron nitride particles having the graphene oxide adsorption layer. USE - The surface-modified hexagonal boron nitride particles are used for a thermally conductive resin composition. ADVANTAGE - The surface-modified hexagonal boron nitride particles have resin affinity with increased adsorption amount by partially reduced graphene oxide adsorption layer regardless of the manufacturing method, particle shape and size of hexagonal boron nitride particles, and excellent properties. The surface-modified hexagonal boron nitride particles are possible to provide a thermally conductive resin composition having more excellent mechanical strength and thermal conductivity. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for producing surface-modified hexagonal boron nitride particles, involving adding a reducing agent to the graphene oxide aqueous dispersion to prepare a partially reduced graphene oxide aqueous dispersion, mixing a powder of surface-untreated hexagonal boron nitride particles with the partially reduced graphene oxide aqueous dispersion until the supernatant is no longer colored, and recovering and drying the solid from the liquid.