▎ 摘　　要

NOVELTY - Preparing conductive polymer-based composite electrode material, comprises respectively preparing high carbon-containing polymer spinning solution, dodecylbenzenesulfonic acid doped conductive polymer spray solution and titanium dioxide precursor spinning solution, adding graphene to at least one of the high carbon-containing polymer spinning solution or the dodecylbenzenesulfonic acid-doped conductive polymer spray solution, alternately depositing the high carbon-containing polymer spinning solution, the dodecylbenzenesulfonic acid-doped conductive polymer spray solution and titanium dioxide precursor spinning solution on the aluminum foil by electrostatic spraying and electrospinning technology at a preset flow rate, evaporating the solvent and removing the aluminum foil to obtain high carbon-containing polymer fibers, pre-oxidizing and carbonizing the composite membrane. USE - The method is useful for preparing conductive high polymer matrix composite electrode material which is useful in energy storage electrode material including carbon material/PANI super capacitor electrode material. ADVANTAGE - The conductive polymer-based composite electrode material has excellent electrochemical performance.