• 专利标题:   Boron nitride-coated sulfonated graphene-epoxy resin composite material for electronic packaging materials, comprises epoxy resin powder, boron nitride powder, sulfonated graphene powder, silane coupling agents, and polyamide curing agent.
  • 专利号:   CN108659457-A
  • 发明人:   CHEN Q, DING X, NI R, DUAN M, LI H
  • 专利权人:   UNIV NANJING SCI TECHNOLOGY
  • 国际专利分类:   C08L063/00, C08K013/06, C08K009/06, C08K003/38, C08K009/02, C08K003/04, C08G059/44
  • 专利详细信息:   CN108659457-A 16 Oct 2018 C08L-063/00 201880 Pages: 11 Chinese
  • 申请详细信息:   CN108659457-A CN10193557 28 Mar 2017
  • 优先权号:   CN10193557

▎ 摘  要

NOVELTY - Boron nitride-coated sulfonated graphene-epoxy resin composite material comprises 65-85 pts. wt. epoxy resin powder, 10-30 pts. wt. boron nitride powder, 1-5 pts. wt. sulfonated graphene powder, 0.5-2.5 pts. wt. silane coupling agents, and 1-10 pts. wt. low molecular weight polyamide curing agent. USE - The composite material is useful for electronic packaging materials. ADVANTAGE - The composite material has excellent thermal conductivity, good dielectric property and excellent thermal stability. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing boron nitride coated sulfonated graphene-epoxy composite material, comprising (i) dissolving silane coupling agent in 95% ethanol solution, stirring and hydrolyzing, adding boron nitride powder according to silane coupling agent mass ratio of 100:1.2-1.8, stirring in a water bath at 80 degrees C, cooling, filtering, washing and drying to obtain modified boron nitride powder; (ii) ultrasonically dispersing the modified boron nitride powder and the sulfonated graphene powder in a mass ratio of 10:1-3, respectively, adding the two dispersions dropwise, mixing, by electrostatic self-assembly, coating the boron nitride particles on the surface of the sulfonated graphene, stirring and mixing uniformly at normal temperature, and drying to obtain boron nitride/sulfonated graphene composite powder; (iii) heating the epoxy resin at 40-60 degrees C to improve its flow properties, adding low molecular weight polyamide curing agent, and spraying the resin onto the substrate in a vacuum environment on the surface, a single layer of resin layer having a thickness of 1-3 mu m is formed, and uniformly spraying boron nitride/sulfonated graphene onto the surface of the resin layer to form a single layer, spraying thermally conductive filler layer with the resin and boron nitride/sulfonated graphene.