• 专利标题:   Surface molecularly imprinted polyionic liquid used e.g. for manufacturing electrochemical sensors for detecting 4-nonylphenol, includes nitrogen-doped graphene-carbon nanotube nitride composite, crosslinking agent and template molecule.
  • 专利号:   CN105017482-A, CN105017482-B
  • 发明人:   LI L, LI Q, ZENG Y, ZHU X, ZHANG J, LI Z
  • 专利权人:   JIAXING COLLEGE, UNIV JIAXING
  • 国际专利分类:   B01J020/26, B01J020/30, C08F222/14, C08F226/06, C08J009/26, C08K003/04, C08K007/24, G01N027/26
  • 专利详细信息:   CN105017482-A 04 Nov 2015 C08F-226/06 201612 Pages: 20 Chinese
  • 申请详细信息:   CN105017482-A CN10354875 23 Jun 2015
  • 优先权号:   CN10354875

▎ 摘  要

NOVELTY - Surface molecularly imprinted polyionic liquid comprises nitrogen-doped graphene-carbon nanotube nitride composite, functional monomer, crosslinking agent and template molecule; prepared by polymerizing under the action of initiator, and removing template molecule. The functional monomer is brominated 1-vinyl-3-ethyl imidazole. The crosslinking agent is ethanediol dimethylacrylate and brominated 1,4-butane-3,3'-bis-1-vinyl imidazole. The template molecule is 4-nonylphenol. USE - Surface molecularly imprinted polyionic liquid used for manufacturing electrochemical sensors for detecting 4-nonylphenol (claimed) and nitrogen-doped graphene/carbon nanotube-molecularly imprinted polymer sensor. ADVANTAGE - The sensor has good adsorption capacity and selectivity, 4-nonylphenol detection range of 0.01-10 mu M and detection limit of 0.005 mu M.