• 专利标题:   Preparation of graphene-coated magnetic nano nickel particles involves stirring liquid acrylonitrile oligomer solution, heat-treating, adding obtained oligomer and nickel compound to solvent, mixing, drying and calcining.
  • 专利号:   CN104096836-A, CN104096836-B
  • 发明人:   HE C, LI X, LIAO C, LIU J, REN X, XU J, ZHANG Q
  • 专利权人:   LIU J, SHENZHEN EIGEN EQUATION GRAPHENE TECHNOL
  • 国际专利分类:   B22F001/02, H01F001/01
  • 专利详细信息:   CN104096836-A 15 Oct 2014 B22F-001/02 201503 Pages: 11 Chinese
  • 申请详细信息:   CN104096836-A CN10246157 05 Jun 2014
  • 优先权号:   CN10246157

▎ 摘  要

NOVELTY - Preparation of graphene-coated magnetic nano nickel particles involves stirring liquid acrylonitrile oligomer (LPAN) solution at 100-200 degrees C for 100-200 hours, heat-treating, adding obtained thermally-oxidized polyacrylonitrile oligomer and nickel compound to a solvent, mixing uniformly, drying obtained LPAN-coated nickel compound at 200-250 degrees C for 1-10 hours until solvent is completely evaporated, and calcining obtained low-temperature carbonization precursor-coated nickel compound at 700-1500 degrees C for 1-10 hours in an inert gas protection atmosphere. USE - Preparation of graphene-coated magnetic nano nickel particles (claimed). ADVANTAGE - The method enables economical preparation of graphene-coated magnetic nano nickel particles having uniform particle size, with high purity and yield, by simple method. DETAILED DESCRIPTION - Preparation of graphene-coated magnetic nano nickel particles involves stirring liquid acrylonitrile oligomer (LPAN) solution at 100-200 degrees C for 100-200 hours, heat-treating obtained micro-cyclized LPAN solution at 200-300 degrees C for 1-10 hours, adding obtained trapezoidal structure thermally-oxidized polyacrylonitrile oligomer and nickel compound to a solvent, mixing uniformly, drying obtained LPAN-coated nickel compound at 200-250 degrees C for 1-10 hours until solvent is completely evaporated, and calcining obtained low-temperature carbonization precursor-coated nickel compound at 700-1500 degrees C for 1-10 hours in an inert gas protection atmosphere with gas flow rate of 10-500 ml/minute.