• 专利标题:   Functionalized graphene oxide, e.g. for electronic devices, comprises predetermined range of basal plane fraction of carbon atoms in sp2-hybridized state and surface functionalized with predetermined concentration of functional groups.
  • 专利号:   WO2009085015-A1, KR2010117570-A, US2011052813-A1, US9156701-B2
  • 发明人:   CHIA P, CHUA L, GOH G S, HO P, WANG S, CHUA R, CHIA P J, GO G S
  • 专利权人:   UNIV SINGAPORE NAT, HO P, CHUA L, WANG S, CHIA P, GOH G S
  • 国际专利分类:   C01B031/04, C07B041/00, C09D005/24, H01L029/12, H01L029/40, C01B031/02, B05D005/00, C07C309/14, B82Y030/00, B82Y040/00
  • 专利详细信息:   WO2009085015-A1 09 Jul 2009 C01B-031/04 200948 Pages: 39 English
  • 申请详细信息:   WO2009085015-A1 WOSG000001 03 Jan 2009
  • 优先权号:   US018751P, KR716175, US735328

▎ 摘  要

NOVELTY - A functionalized graphene oxide has a basal plane fraction of carbon atoms in the sp2-hybridized state of 0.1-0.9. The remainder fraction of carbon atoms comprises sp3-hybridized carbon atoms which are bonded to oxygen groups, preferably hydroxyl, epoxy and/or carboxylic acid. The surface of the graphene oxide is functionalized with functional group(s) at a concentration greater than one functional group per 100 carbon atoms and less than one functional group per six carbon atoms. USE - A functionalized graphene oxide for use in a functionalized graphite oxide in the form of a liquid dispersion for electrically-conductive or heat-conductive coatings or formulations, infrared-emitting coatings, electrodes for devices, electrochemically active electrode in batteries, or semiconductor in field-effect transistors (claimed). ADVANTAGE - The functional groups render the graphene oxide more water-soluble or more organo-soluble. The material is dispersible at higher than 5 (preferably higher than 15) mg/mL in solvent without aggregating or precipitating over extended periods at room temperature. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: (1) a method of making the functionalized graphite oxide comprising oxidizing graphite to form graphite oxide, where the graphene sheets which make up the graphite have a basal plane fraction of carbon atoms in the sp2-hybridized state of 0.1-0.9; and exfoliating and in-situ functionalizing the graphite oxide surface with functional group(s) such that functionalization of the surface is effected at a concentration greater than one functional group per 100 carbon atoms and less than one functional group per six carbon atoms; (2) a material made of oxygen-containing graphene nanosheets surface-grafted with organic-soluble or water-soluble and capable of forming stable dispersions at high concentrations in organic or water-based solvents, where the ratio of oxygen atoms bonded to the graphene oxide nanosheet to the carbon atoms in the graphene nanosheet is sub-stoichiometric, i.e. oxygen-to-carbon ratio is less than 1:2; and (3) a method of making the material by chemical oxidation of bulk graphite, followed by exfoliation and in-situ functionalization with the desired surface-grafted components, followed by purification. DESCRIPTION OF DRAWING(S) - The drawing shows a graph of an X-ray diffraction of graphite oxide.