• 专利标题:   MXene-based conductive self-cleaning composite fabric for electromagnetic shielding, has porous fabric substrate, MXene-based conductive functional layer, rough micro-nano particles and silicone rubber composite layer.
  • 专利号:   CN114855442-A
  • 发明人:   LI P, SUN H, ZHANG Y, ZHAO P, ZHENG Y, HAN W, ZHANG G
  • 专利权人:   UNIV QINGDAO SCI TECHNOLOGY
  • 国际专利分类:   D06M101/06, D06M101/28, D06M101/32, D06M101/34, D06M011/38, D06M011/46, D06M011/74, D06M011/79, D06M015/643
  • 专利详细信息:   CN114855442-A 05 Aug 2022 D06M-011/74 202287 Chinese
  • 申请详细信息:   CN114855442-A CN10517378 13 May 2022
  • 优先权号:   CN10517378

▎ 摘  要

NOVELTY - The MXene-based conductive self-cleaning composite fabric for electromagnetic shielding has a porous fabric substrate, an MXene-based conductive functional layer, rough micro-nano particles and a silicone rubber composite layer. The MXene-based conductive functional layer is coated on the surface of the porous fabric substrate. The rough micro-nano particles grow on the surface of the MXene-based conductive functional layer in situ. The silicone rubber layer covers the rough micro-nano particles to form the rough micro-nano particles and the silicone rubber composite layer. USE - MXene-based conductive self-cleaning composite fabric for electromagnetic shielding. ADVANTAGE - Tests show that the composite fabric material has high conductivity and electromagnetic shielding performance, and the electromagnetic shielding performance value of the composite fabric material in an X wave band can be as high as 58.4dB under the optimal condition; meanwhile, the super-hydrophobic self-cleaning function of the composite conductive fabric endows the composite conductive fabric with excellent environmental stability (such as water resistance/dust prevention/ice prevention/rain and snow prevention) and ideal mechanical/wear-resistant/corrosion-resistant stability. Therefore, the multifunctional conductive self-cleaning composite fabric disclosed by the invention can be applied to the related fields of high-efficiency electromagnetic shielding, electromagnetic wave absorption and the like in a complex and harsh environment. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a preparation method of the MXene-based conductive self-cleaning composite fabric for electromagnetic shielding which involves: coating the MXene/carbon nano material dispersion liquid or the MXene dispersion liquid on the surface of the pretreated porous fabric substrate in a multi-coating mode, and drying to obtain a stable MXene/carbon nano material conductive functional coating or an MXene conductive functional coating on the surface of the fabric; generating silica particles or titanium dioxide particles with a micro-nano hierarchical structure on the surface of the conductive functional coating in situ by using a sol-gel method; and coating the low-surface-energy silicone rubber solution on the surface of the conductive coating with the rough structure, and then vulcanizing to obtain the super-hydrophobic self-cleaning multifunctional composite fabric. DESCRIPTION OF DRAWING(S) - The drawing shows scanning electron microscope image of the raw polyester fabric (a) and the conductive self-cleaning composite fabric (b).