• 专利标题:   Preparing a graphene-ionic liquid composite sulfur adsorbent useful in methane desulfurization, comprises e.g. adding cationic salt and bromoalkane and reacting, performing suction filtration and washing to obtain cationic bromide and ultrasonic dispersing of graphene oxide in acetone solvent.
  • 专利号:   CN115970651-A
  • 发明人:   JI K, XUN Q, LIU X, WEI Z, ZHU T, WANG K, ZHANG W, XU F, HOU Q
  • 专利权人:   SHANDONG NONMETALLIC MATERIAL RES INST
  • 国际专利分类:   B01J020/22, B01J020/30, C10L003/10
  • 专利详细信息:   CN115970651-A 18 Apr 2023 B01J-020/22 202346 Chinese
  • 申请详细信息:   CN115970651-A CN11075773 02 Sep 2022
  • 优先权号:   CN11075773

▎ 摘  要

NOVELTY - Preparing a graphene-ionic liquid composite sulfur adsorbent, comprises (1) adding cationic salt and bromoalkane, stirring and reacting for 16-24 hours at 50-70℃, performing suction filtration and washing with ethanol to obtain cationic bromide, (2) carrying out ultrasonic dispersing of graphene oxide in an acetone solvent, and then adding cationic bromine salt and NaBF4, introducing nitrogen for protection, stirring and reacting for 16-24 hours at 50-70℃, performing suction filtration, washing with dichloromethane and drying to obtain a product, and (3) dispersing the product in water, adding neutral salt, stirring uniformly, adding a hydrazine hydrate solution and an ammonia aqueous solution, reacting for 6-12 hours at the temperature of 80-120℃, centrifuging, washing with water and freeze-drying to obtain the final product. USE - The graphene-ionic liquid composite sulfur adsorbent is useful in methane desulfurization (claimed). ADVANTAGE - The adsorbent: can adsorb the thiophene aromatic hydrocarbon sulfide in methane; and solve the problem of purification of methane propellant.