• 专利标题:   Preparation of three-dimensional molecularly imprinted photocatalytic composite material used in wastewater treatment, involves prepolymerizing solution of p-nitrophenol and pyrrole on bismuth oxyiodide, and mixing with graphene oxide.
  • 专利号:   CN104971748-A, CN104971748-B
  • 发明人:   TIAN L, ZHANG W, CHEN P, JIANG H, LI M, BAI P
  • 专利权人:   UNIV NANCHANG HANGKONG
  • 国际专利分类:   B01J027/06, B01J035/10, C02F001/30, C02F001/58, C02F101/34, C02F101/38
  • 专利详细信息:   CN104971748-A 14 Oct 2015 B01J-027/06 201615 Pages: 9 Chinese
  • 申请详细信息:   CN104971748-A CN10416375 16 Jul 2015
  • 优先权号:   CN10416375

▎ 摘  要

NOVELTY - Preparation of three-dimensional molecularly imprinted photocatalytic composite material involves preparing bismuth oxyiodide nanoparticles using bismuth nitrate, potassium iodide and polyvinylpyrrolidone-K30 as raw materials, dissolving p-nitrophenol and pyrrole in liquid mixture of methanol and distilled water, stirring, prepolymerizing resultant solution on surface of the prepared particles using iron(II) chloride as catalyst, eluting using sodium hydroxide solution, and mixing obtained product and graphene oxide in a mass ratio of 100:5-100:100. USE - Preparation of three-dimensional molecularly imprinted photocatalytic composite material used in degradation of organic pollutants in wastewater treatment. ADVANTAGE - The method enables efficient preparation of three-dimensional molecularly imprinted photocatalytic composite material having excellent selective decomposition capability with respect to organic pollutants in wastewater treatment. DETAILED DESCRIPTION - Preparation of three-dimensional molecularly imprinted photocatalytic composite material involves preparing bismuth oxyiodide nanoparticles using bismuth nitrate, potassium iodide and polyvinylpyrrolidone-K30 as raw materials, dissolving p-nitrophenol and pyrrole in liquid mixture of methanol and distilled water in a volume ratio of 1:1, stirring in dark for 30 minutes, prepolymerizing resultant solution on surface of the prepared particles using iron(II) chloride as catalyst, eluting using sodium hydroxide solution, forming imprinting hole, and mixing obtained product and graphene oxide in a mass ratio of 100:5-100:100.