• 专利标题:   Removal of carbon monoxide of graphene oxide supported gold platinum catalyst by stirring graphite powder and sulfuric acid in oil bath, vacuum suction-filtering, adding chloroauric acid and chloroplatinic acid, centrifuging and reacting.
  • 专利号:   CN104923220-A
  • 发明人:   LEI C, ZHANG F
  • 专利权人:   UNIV CHANGZHOU
  • 国际专利分类:   B01D053/62, B01D053/86, B01J023/52
  • 专利详细信息:   CN104923220-A 23 Sep 2015 B01J-023/52 201603 Pages: 5 Chinese
  • 申请详细信息:   CN104923220-A CN10328936 13 Jun 2015
  • 优先权号:   CN10328936

▎ 摘  要

NOVELTY - Removal of carbon monoxide of graphene oxide supported gold platinum catalyst comprises taking graphite powder, pouring into sulfuric acid, stirring in oil bath, adding potassium sulfate and phosphorus pentoxide, stirring, vacuum suction-filtering, slowly adding concentrated sulfuric acid and potassium permanganate to filtrate, stirring at 35 degrees C for 2 hours, removing upper layer, adding chloroauric acid solution and chloroplatinic acid solution, stirring under vibration, centrifuging, adding urea, ferric hydroxide and nickel hydroxide, stirring, reacting, adding dispersant and drying. USE - Method for removing carbon monoxide of graphene oxide supported gold platinum catalyst (claimed). ADVANTAGE - The method has simple operation, no secondary environmental pollution, and has carbon monoxide removal rate of more than 99.7%. DETAILED DESCRIPTION - Removal of carbon monoxide of graphene oxide supported gold platinum catalyst comprises taking 3-5 g graphite powder, pouring into 12-15 mL sulfuric acid, stirring in oil bath at 75-80 degrees C, adding 2.5-3.0 g potassium sulfate and 2.5-3.0 g phosphorus pentoxide, stirring for 4.5-6.5 hours, vacuum suction-filtering by 0.2 mm microporous film, slowly adding 120-125 mL concentrated sulfuric acid and 15-18 g potassium permanganate to filtrate, stirring at 35 degrees C for 2 hours, removing upper layer, adding 20-30 mL of 0.5 mol/L chloroauric acid solution and 25-40 mL of 0.6 mol/L chloroplatinic acid solution, stirring under vibration, centrifuging, adding 5-15 g urea, 3-8 g ferric hydroxide and 5-10 g nickel hydroxide, stirring, reacting for 10-30 minutes, adding 3-5 g dispersant and drying at 105-110 degrees C for 1.5 hours. The dispersant is zinc stearate, magnesium stearate or barium stearate.