• 专利标题:   Preparation method of supported nano metal catalyst useful in reaction of preparing lower alcohols from synthesis gas comprises mixing graphene oxide, heating and calcining.
  • 专利号:   CN112191253-A
  • 发明人:   MA P, ZHU X, TAN Y, BAO J
  • 专利权人:   UNIV CHINA SCI TECHNOLOGY
  • 国际专利分类:   B01J023/86, B01J035/10, C07C029/156, C07C031/02, C07C031/04, C10L001/02
  • 专利详细信息:   CN112191253-A 08 Jan 2021 B01J-023/86 202110 Pages: 10 Chinese
  • 申请详细信息:   CN112191253-A CN11109455 16 Oct 2020
  • 优先权号:   CN11109455

▎ 摘  要

NOVELTY - Preparation method of supported nano metal catalyst comprises (i) mixing graphene oxide, aqueous solution containing metal ions with reducing agent, adjusting pH to 10-12, and then heating for hydrothermal reaction to obtain a catalyst precursor, where the metal ions include copper ions, cobalt ions and doped metal ions and the doped metal ion is a trivalent metal ion; and (ii) heating and calcining the catalyst precursor to obtain a supported nano metal catalyst. USE - The catalyst is useful in the reaction of preparing lower alcohols from synthesis gas (claimed). ADVANTAGE - The method improves the stability and product selectivity. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for (1) supported nano metal catalyst comprising a carrier and nano metal particles supported on the carrier, where the carrier is reduced graphene oxide, the nano metal particles include copper, cobalt and doped metals and doping metal is a metal element whose valence may be trivalent; and (2) use of supported nano-metal catalyst prepared as mentioned above in the reaction of preparing lower alcohols from synthesis gas.